heteropoly acids (hpa) and their salts have advantages as catalysts which make them both economically and environmentally attractive, strong br?nsted acidity, exhibiting fast reversible multi-electron redox transformations under rather mild conditions, very high solubility in polar solvents, fairly high thermal stability in the solid states, and efficient oxidizing ability, so that they are imp...

o-گلیکوپروتئین2-استامینو-2-دی اکسی-?-d-گلوکوپیرانوزیداز (o-glcnacase) مسئول هیدرولیز باقیمانده های ?-n-استیل گلوکوزامین (o-glcnac) از باقیمانده های سرین یا ترئونین پروتئین نوکلئوسیتوپلاسمیک است. در این مطالعه مکانیسم کاتالیزوری آنـزیم o-glcnacase با استفاده از نظریه تابعی چگالی (dft) در سطح b3lyp و سری پایه **6.311g مطالعه و بررسی شد. همچنین اثرات جانشینی فلوئور روی گروه 2-استامیدوی سوبسترا در ...

in this thesis a calibration transfer method is used to achieve bilinearity for augmented first order kinetic data. first, the proposed method is investigated using simulated data and next the concept is applied to experimental data. the experimental data consists of spectroscopic monitoring of the first order degradation reaction of carbaryl. this component is used for control of pests in frui...

this work is presented in five parts. in the first part preparation of the starting complex [pt(c^n)cl(dmso)], 1, in which c^n = n(1),c(2?)-chelated, deprotonated 2-phenylpyridine, and dmso = dimethylsulfoxide, and its reaction with 1 equiv of the biphosphine ligands bis(diphenylphosphino)amine, dppa, or bis(diphenylphosphino)methane, dppm, to give the complex [pt(c^n)cl(dppa)], 2, or [pt(c^n)c...

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