In this research, the adsorption destructive process of chlorpyrifos (CP,O,O-Diethyl-O-3,5,6-trichloro-2-pyridinyl phosphorothioate) as a noticeable organophosphate pesticide using in agriculture on the nickel tungstate (NiWO4) nanoparticles catalyst was investigated and monitored via the 31P nuclear magnetic resonance (31PNMR). The effects of various experimental parameters such as catalyst do...

In this research, the adsorption destructive process of chlorpyrifos (CP,O,O-Diethyl-O-3,5,6-trichloro-2-pyridinyl phosphorothioate) as a noticeable organophosphate pesticide using in agriculture on the nickel tungstate (NiWO4) nanoparticles catalyst was investigated and monitored via the 31P nuclear magnetic resonance (31PNMR). The effects of various experimental parameters such as catalyst do...

Exosomes emerge as central 3'-->5' RNA processing and degradation machineries in eukaryotes and archaea. We determined crystal structures of two 230 kDa nine subunit archaeal exosome isoforms. Both exosome isoforms contain a hexameric ring of RNase phosphorolytic (PH) domain subunits with a central chamber. Tungstate soaks identified three phosphorolytic active sites in this processing chamber....

in this research, the adsorption destructive process of chlorpyrifos (cp,o,o-diethyl-o-3,5,6-trichloro-2-pyridinyl phosphorothioate) as a noticeable organophosphate pesticide using in agriculture on the nickel tungstate (niwo4) nanoparticles catalyst was investigated and monitored via the 31p nuclear magnetic resonance (31pnmr). the effects of various experimental parameters such as catalyst do...

The CMS crystal calorimeter, comprising about 80,000 scintillating lead tungstate crystals read out by avalanche photodiodes (in the barrel) and vacuum phototriodes (in the endcap), is designed to give excellent energy resolution in the demanding LHC environment. It is now entering the construction phase. A status report on the project is presented, including recent results from test beam verif...

Loss compensation in long-range dielectric-loaded surface plasmon-polariton waveguides is theoretically analyzed when rare-earth-doped double tungstate crystalline material is used as the gain medium in three different waveguide configurations. We study the effect of waveguide geometry on loss compensation at the telecom wavelength of 1.55 μm, and demonstrate that a material gain as small as 12...

Mode-locked operation of a simple Yb:KGW (potassium gadolinium tungstate) oscillator is described, providing 10 W at 1039 nm with a 290 fs pulse width. A polarization-coupled scheme is used for efficient longitudinal pumping by a pair of reshaped laser diode bars. With changes in cavity dispersion, the pulse width is adjustable from 134 to 433 fs, in a high-quality circular mode. A saturable ab...

The solid state reaction of CUWO4-2 formation from CuO and WO3 was studied by the contact method in air and nitrogen. The results showed that the reaction is governed by the diffusion of the W 6 + and 0 2 _ ions and that the rate determining step is the diffusion of oxygen ions in the reaction product. This is in agreement with the defect structure of copper tungstate, an n-type semiconductor w...

Abstract Organic esters of phosphoric acid and other organophosphorous compounds are enzymatically hydrolyzed during wastewater treatment by microbial phosphoesterases, especially phosphomonoesterase (phosphatase). For physiological reasons, the enzyme is inhibited its main inorganic reaction product, ortho-phosphate. It known that oxyanions transition metals, resembling molecular topology orth...

The binary phase relations ofseveral naturally-occurring tungstats mins14ls, ofthe general form M2*WOae w€t€ investigated hydrothermally at fluid pressure of 1.0 kbar and temperatures of 400o-900oc. A complete solid solution, with tetragonal symmetry, between scheelite (M2* Ca) and Stolzite (Pb) forms above725"C. The solvus is alnost symmetrical with a crest near CaorPbrr. The observed linear v...