نتایج جستجو برای: thermodynamic and kinetic interaction
تعداد نتایج: 16897216 فیلتر نتایج به سال:
asymmetric membranes are widely used in many industrial membrane separation processes. the major advantage of membrane filtration over the conventional process is its ability to remove a wider spectrum of particles without using any chemicals. hollow fiber configuration offer many advantages over flat-sheet or tubular membranes. the spinning process of hollow fiber may look simple, yet it is te...
in this work, one and two-dimensional lattices are studied theoretically by a statistical mechanical approach. the nearest and next-nearest neighbor interactions are both taken into account, and the approximate thermodynamic properties of the lattices are calculated. the results of our calculations show that: (1) even though the next-nearest neighbor interaction may have an insignificant effect...
living organisms can sense and respond to external and internal stimuli. response isdemonstrated in many forms including modulation of gene expression profiles, motility,secretion, cell death, etc. nevertheless, all forms share a basic property: they depend on sensingsmall changes in the concentration of an effector molecule or subtle conformational changes ina protein and invoking the appropri...
New chlorido-dimethylsulfoxide-iridium(III), ruthenium(III) and rhodium(III) complexes with the 2-(1H-pyrazol-1-yl)-pyrimidine (pyrapyr) ligand (OC-6-N1)-[Rh(III)Cl3(DMSO-κS)(pyrapyr)] (1a, N = 3 and 1b, N = 4); (OC-6-N1)-[Ru(III)Cl3(DMSO-κS)(pyrapyr)] (2a, N = 3 and 2b, N = 4) and (OC-6-N1)-[Ir(III)Cl3(DMSO-κS)(pyrapyr)] (3a, N = 3 and 3b, N = 4) have been synthesized and characterized by spec...
In this paper we used a previously reported model for examining the adsorption of nonelectrolytes in solution by solid adsorbents to study the adsorption of lithium(I) cations by acid and sodium amberlites, which is an ion-exchange process. Based on the results, both are equilibrium processes and obey a kinetic law with a unity partial order in the Li+ concentration. The kinetic results were us...
The determination of kinetic and thermodynamic data from hyperthermophilic enzymes at physiological temperature (i. e. ‡ 80 C) raises a number of technical and fundamental problems. Based on studies of purified enzymes from the model organism Pyrococcus furiosus several of these problems are identified and explored here. It is proposed that kinetic and thermodynamic data on hyperthermophilic en...
Chapman-Enskog expansion is the orthodox approach to derive continuum flow models from Boltzmann’s kinetic equation for dilute gases. Beyond the Navier-Stokes-Fourier order, these models known as Burnett hydrodynamic-regime equations violate a number of fundamental mechanical and thermodynamic principles in their original forms. This has generated a widely investigated problem in the kinetic th...
The critical radius of a nucleus grown by diffusion in a solution is studied thermodynamically as well as kinetically. The thermodynamic growth equation called Zeldovich equation of classical nucleation theory and the kinetic diffusional growth equation combined with the Ostwald-Freundlich boundary condition lead to the same critical radius. However, it should be pointed out that the diffusiona...
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