the kinetics of hydrogen evolution reaction (her) was studied in 1m naoh at various temperatures (298 to 358 k) on ni-p-c (composite electrodes. the electrochemical efficiency of the electrodes has been evaluated on the basis of electrochemical data obtained from the steady-state polarization tafel curves, electrochemical impedance spectroscopy (eis) and cyclic voltammetry (cv) in 1m naoh solut...

In this study ternary Ni-P-CeO2 catalysts were first synthesized by the Co-electrodeposition method on a copper substrate and then characterized by means of microstructural and electrochemical techniques toward a hydrogen evolution reaction (HER). Also, for comparison other catalysts such as Ni-CeO2, Ni-P, and Ni were prepared and characterized by the same methods. The microstructure of the inv...

A comparison is made between electrochemical and homogeneous redox reactivity for species involving the transfer of multiple electrons at a single thermodynamic potential. In the electrochemical case the coreactant is the electrode; in the homogeneous case it is any of several members of a homologous series of one-electron reagents. In the latter case it is shown that the slope of a plot of the...

in this work, electrochemical methods such as tafel polarization and electrochemical impedance spectroscopy (eis) were used to study the inhibition efficiency of nettle leaves hydroalcoholic extract as a green corrosion inhibitor of api 5l carbon steel in 0.5 m h2so4 solution. the results showed that the inhibition efficiency was increased with increasing the concentration of the extract and th...

We present a detailed mechanistic study of HER at the sulfur vacancy VS 2H–MoS2. evaluate Volmer, Tafel, and Heyrovsky transition states for different possible reaction steps, determining activation energy as function electrochemical potential via grand-canonical density functional theory. The results show that Volmer steps depend on energies decrease more negative potentials, while this is not...

The kinetics of hydrogen evolution reaction (HER) was studied in 1M NaOH at various temperatures (298 to 358 K) on Ni-P-C (composite electrodes. The electrochemical efficiency of the electrodes has been evaluated on the basis of electrochemical data obtained from the steady-state polarization Tafel curves, electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) in 1M NaOH solut...

chromate conversion coating is applied on aluminum 6061. the optimum conditions for chromate bath composition and immersion time are also obtained for standard requirements provision such as corrosion resistance in salt spray test, electrical resistance and coating quality. the applied coatings are electrochemically tested in sea and distilled water. according to tafel and cyclic polarization c...