"Proton-collecting antenna" are conjectured to consist of several carboxylates within hydrogen-bond (HB) networks on the surface of proteins, which funnel protons to the orifice of an internal proton wire leading to the protein's active site. Yet such constructions were never directly visualized. Here we report an X-ray structure of green fluorescent protein (GFP) of the highest resolution to d...

Reactive mineral-water interfaces exert control on the bioavailability of contaminant arsenic species in natural aqueous systems. However, the ability to accurately predict As surface complexation is limited by the lack of molecular-level understanding of As-water-mineral interactions. In the present study, we report the structures and properties of the adsorption complexes of arsenous acid (As...

Background & Aims of the Study: Saveh city -located in the semi-arid area in Iran- has brackish water and it was forced to use reverse osmosis desalting systems.  Water is not distributed through the distribution network to homes so, people have to buy water from certain places and transfer water through household storage vessel. They have to buy more water and keep it at home for more than 1 w...

Although perovskite oxides hold promise in applications ranging from solid oxide fuel cells to catalysts, their surface chemistry is poorly understood at the molecular level. Here we follow the formation of the first monolayer of water at the (001) surfaces of Sr(n+1)Ru(n)O3(n+1) (n = 1, 2) using low-temperature scanning tunnelling microscopy, X-ray photoelectron spectroscopy, and density funct...

Electrolytes interact with water in many ways: changing dipole orientation, inducing charge transfer, and distorting the hydrogen-bond network in the bulk and at interfaces. Numerous experiments and computations have detected short-range perturbations that extend up to three hydration shells around individual ions. We report a multiscale investigation of the bulk and surface of aqueous electrol...

Conjugate-base anions are ubiquitous in aqueous solution. Understanding the hydration of these anions at the molecular level represents a long-standing goal in chemistry. A molecular-level perspective on ion hydration is also important for understanding the surface speciation and reactivity of aerosols, which are a central component of atmospheric and oceanic chemical cycles. In this Account, a...

according to the low efficiency of irrigation and drainage networks and water distribution in iran, simulating water flow and sensitivity structures and networks is considered as a new approach to evaluate the performance hydroelectric projects in the country. in this study, because of reduced water supply and distribution, especially in downstream irrigation and drainage networks varamin to ev...

in this work, response surface methodology (rsm) and artificial neural network (ann) were used to predict the decolorization efficiency of reactive red 33 (rr 33) by o3/uv process in a bubble column reactor. the effects of four independent variables including time (20-60 min), superficial gas velocity (0.06-0.18 cm/s), initial concentration of dye (50-150 ppm) and ph (3-11) were investigated us...