The production of porous polymers is often solvent intensive. As environmental regulations become more stringent, there is a need to consider cleaner routes to these materials. Carbon dioxide has emerged as a clean and versatile solvent for the synthesis and processing of a range of polymers(1). CO2 is inexpensive, non-toxic, non-flammable, and easily separated from products. This review focuse...

The antifungal properties of two silver-coated natural cotton fiber structures prepared using a supercritical carbon dioxide (scCO2) solvent were examined. Scanning electron microscopy confirmed that the scCO2 process may be used to produce cotton fiber textiles with uniform silver nanoparticle coatings. A version of the Kirby-Bauer disk diffusion test was used to assess the ability of these te...

Geological carbon dioxide storage must be designed such that the CO2 cannot escape from the rock formation into which it is injected, and often simple stratigraphic trapping is insufficient. CO2 can be trapped in the pore space as droplets surrounded by water through capillary trapping. X-ray microtomography was used to image, at a resolution of 6.6 m, the pore-scale arrangement of these drople...

Even in the context of hydrocarbons' general resistance to selective functionalization, methane's volatility and strong bonds pose a particular challenge. We report here that silver complexes bearing perfluorinated indazolylborate ligands catalyze the reaction of methane (CH(4)) with ethyl diazoacetate (N(2)CHCO(2)Et) to yield ethyl propionate (CH(3)CH(2)CO(2)Et). The use of supercritical carbo...

Cu films were deposited onto planar and etched silicon substrates by the hydrogen-assisted reduction of a series of copper(I)(1,1,1,5,5,5-hexafluoro-2,4-acetylacetonate)L compounds [Cu(I)(hfac)L] where L is (2butyne), (1,5-cyclooctadiene), (vinyltrimethylsilane) or (2-methyl-1-hexene-3-yne) in supercritical solvents using a cold wall, high pressure reactor. At substrate temperatures of 225 8C a...

Novel foods and novel processing techniques are a real challenge for science, industry and administrative bodies but are not a threat to consumers, so although the question why consumers are very wary of ‘novel food’ is undoubtedly interesting, this paper does not deal with consumer attitudes but with definitions of ‘foods’, ‘functional foods’ and ‘novel foods’ and with particular issues regard...

We present the development of a high-pressure apparatus for measurements of diffusion coefficients in supercritical fluids. The Taylor dispersion method has been adapted to conduct experiments at the pressures up to 25.0 MPa. In order to test the developed set-up, binary diffusion coefficients D at infinite dilution in supercritical carbon dioxide have been measured for a reference system, benz...

Biodiesel is considered a promising replacement to petroleum-derived diesel. Using oils extracted from agricultural crops competes with their use as food and cannot realistically satisfy the global demand of diesel-fuel requirements. On the other hand, microalgae, which have a much higher oil yield per hectare, compared to oil crops, appear to be a source that has the potential to completely re...

In this letter, we propose a novel low-temperature nitridation technology on a tantalum nitride (TaN) thin film resistor (TFR) through supercritical carbon dioxide (SCCO2) treatment for temperature sensor applications. We also found that the sensitivity of temperature of the TaN TFR was improved about 10.2 %, which can be demonstrated from measurement of temperature coefficient of resistance (T...