In this work, the cholesterol concentration in the supercritical (SC) CO2, under working conditions, is calculated by implementing the modified Peng Robinson equation of state (EoS) combined with the Van Der Waals mixing rules. Here, optimisations of the interaction coefficient (kij) between solvent and solute and the solute critical parameters (i.e. critical pressure and temperature) are the m...

An improved version of the manometric apparatus and its procedures for measuring excess sorption of supercritical carbon dioxide are presented in detail with a comprehensive error analysis. An improved manometric apparatus is necessary for accurate excess sorption measurements with supercritical carbon dioxide due to the difficulties associated with the high sensitivity of density for pressure ...

Garlic (Allium sativum L.) and garlic extracts have therapeutical properties that stem from their sulfur-containing compounds, mainly allicin. The main objective of this work was to compare conventional and “premium” garlic extracts in terms of yield and quality, with the latter being obtained using supercritical carbon dioxide (SC-CO2) as the solvent. Yield ranged between 0.65 and 1.0% and inc...

Techniques involving supercritical carbon dioxide have been successfully used for the formation of drug particles with controlled size distributions. However, these processes show some limitations, particularly in processing aqueous solutions. A diagram walking algorithm based on available experimental data was developed to evaluate the effect of ethanol on the efficiency of water removal proce...

Lipid compounds are gaining increasing attention due to a wide range of applications in the food industry. Particularly, supercritical carbon dioxide (SCCO2) is being successfully employed as a green solvent in the extraction and fractionation of nonpolar lipids. Knowledge of the solubility of pure lipid-type substances and their mixtures in SCCO2 is essential for evaluating the viability of su...

The silicon (Si)/graphene composite has been touted as one of the most promising anode materials for lithium ion batteries. However, the optimal fabrication method for this composite remains a challenge. Here, we developed a novel method using supercritical carbon dioxide (scCO2) to intercalate Si nanoparticles into graphene nanosheets. Silicon was modified with a thin layer of polyaniline, whi...

In this paper yield of nimbin extraction from neem seeds using supercritical carbon dioxide with methanol as co-solvent has been studied. In this case mass transfer coefficient in terms of Sherwood number has been estimated by a neuro-fuzzy network. Then the estimated mass transfer coefficient has been fed to the system model which is set of partial differential equations. The proposed gray box...

The efficiency of high pressure extraction of lutein diesters from marigold (Tagetes erecta) flower petals has been investigated. The solvents used for extraction were supercritical carbon dioxide and liquid propane. Operating parameters were 300 bar and 40, 60 and 80 °C for CO2 and 100, 150, 200 bar and 40 and 60 °C for propane, respectively. The influence of process parameters on the total yi...

In this study, various molecular dynamics simulations were conducted to investigate the effect of supercritical carbon dioxide on the structural integrity of hen egg white lysozyme. The analyses of backbone root-mean-square deviation, radius of gyration, and secondary structure stability all show that supercritical CO(2) exhibits the ability to increase the stability of this protein, probably a...