this work describes the optical and structure properties of nickel sulfide and cobalt sulfide nanoparticles in zsm-5 zeolite. the samples were obtained by sulfidation of the ni2+ and co2+ ion-exchange zsm-5 zeolites in a na2s solution at room temperature. the optical properties of the samples were studied by uv-visible spectroscopy. their crystalline structure and morphology were studied by x-r...

Three experiments involving 296 pigs were conducted to determine the related effects of copper sulfate and ferrous sulfide on performance and liver copper and iron stores of growing-finishing pigs, and the effect of ferrous sulfide on the depletion of copper from the liver. The dietary addition of 250 ppm copper alone improved growth rate by 9.2% (621 vs 678 g/day) and feed to gain ratio by 3.3...

The cycling of sulfur in oil field brines has focused predominantly on bacteria involved in the reduction of sulfur species to sulfides, which are detrimental to the production of these fields. However, recent interest in the addition of nitrates and nitrites to oil field brines for the remediation and control of sulfides has rekindled new interest in sulfide bio-oxidation. Addition of nitrate ...

School of Earth and Ocean Sciences, Cardiff University, Main Building, Park Place, Cardiff CF10 3YE, UK The largest and most significant type of geological deposit of platinum group elements (PGEs) is that associated with magmatic base metal sulfide minerals in layered mafic or ultramafic igneous intrusions.The common association of PGEs with sulfide minerals is a result of processes of magmati...

BACKGROUND Recent evidence suggests that hydrogen sulfide is capable of mitigating the degree of cellular damage associated with ischemia-reperfusion injury. The purpose of this study was to determine whether it is protective in skeletal muscle. METHODS This study used both in vitro (cultured myotubes subjected to sequential anoxia and normoxia) and in vivo (mouse hind-limb ischemia followed ...

Nickel sulfide, nickel oxide, cobalt sulfide, and cobalt oxide were shown to be car cinogenic on single intramuscular injection in rats. The sulfide of each metal induced a significantly higher tumor incidence than did its oxide. Comparisons between average latent periods and between measures of tumor progression also indicated that the presence of the sulfide enhances the carcinogenic activity...

In wetland soils and underwater sediments of marine, brackish and freshwater systems, the strong phytotoxin sulfide may accumulate as a result of microbial reduction of sulfate during anaerobiosis, its level depending on prevailing edaphic conditions. In this review, we compare an extensive body of literature on phytotoxic effects of this reduced sulfur compound in different ecosystem types, an...

This study aimed to investigate the effects of polymorphisms of the flavin-containing mono-oxygenase 3 (FMO3) and flavin-containing mono-oxygenase 6 (FMO6) genes on the pharmacokinetics of sulindac sulfide, the active metabolite of sulindac, in patients with preterm labor. Ten single-nucleotide polymorphisms (SNPs) were genotyped, and plasma sulindac sulfide concentrations were measured at 0, 1...

We examined the use of room-temperature hydrochloric acid (1-6 M) and salt solutions of magnesium chloride, sodium carbonate, and sodium sulfide for the removal of arsenic from synthetic iron monosulfides and contaminated sediments containing acid-volatile sulfides (AVS). Results indicate that acid-soluble arsenic reacts with H2S released from AVS phases and precipitates at low pH as disordered...

In non-cyanogenic species, the main source of cyanide derives from ethylene and camalexin biosyntheses. In mitochondria, cyanide is a potent inhibitor of the cytochrome c oxidase and is metabolized by the β-cyanoalanine synthase CYS-C1, catalyzing the conversion of cysteine and cyanide to hydrogen sulfide and β-cyanoalanine. The hydrogen sulfide released also inhibits the cytochrome c oxidase a...