The thermal conductivity of superconducting MgB 2 was studied in both the superconducting and normal state region. The latter is almost equally determined by the electronic-and the lattice thermal conductivity. In the superconducting state, however, the lattice thermal conductivity is larger. The electronic thermal conductivity below T c was derived from the experimental data considering the Ba...

Turbidity measurements are inexpensive and can be performed rapidly and simply. Therc has bccn a necessity to develope a technique which could bc utiliscd with some degree of confidence to identify certain conditions rclatcd to potentially problcrnalic sugars. Nephelometric turbidity measurements were performed on a number of raw sugars and correlated with filterability dctcrmined routinely usi...

Furfuryl cations are generated via a highly efficient bismuth-catalyzed reaction of furfuryl alcohols. This systematic study provides insight on the reactivity profile of furfuryl cations towards nucleophilic substitution reactions. Novel C-C, C-N, C-O and C-S bond forming reactions of furfuryl cations have been developed, thus providing access to a diverse array of building blocks for further ...

The scope of a recently reported method for the catalytic enantioselective bromochlorination of allylic alcohols is expanded to include a specific homoallylic alcohol. Critical factors for optimization of this reaction are highlighted. The utility of the product bromochloride is demonstrated by the first total synthesis of an antibacterial polyhalogenated monoterpene, (-)-anverene.

Fluorinated polyurethanes with a glass transition temperature as low as -139 °C and a decomposition onset temperature of 247-330 °C were prepared by a reaction of fluorinated alcohols with aromatic and cycloaliphatic diisocyanates in solution or melt.

Friedel-Crafts allylic alkylation of a wide variety of aromatic and heteroaromatic compounds with allylic alcohols catalysed by AuCl(3) (5 mol%) under mild conditions at room temperature was accomplished in good to excellent yields (up to 99%) and regioselectivity.

Sugarcane is one of the world's main carbohydrates sources. We analysed the APSIM-Sugar (AS) and DSSAT/CANEGRO (DC) models to determine their structural differences, and how these differences affect their predictions of crop growth and production. The AS model under predicted yield at the hotter sites, because the algorithm for computing the degree-days is based in only one upper cardinal tempe...

A general strategy for the synthesis of 2-aryl-glycals and their elaboration to 2-C-aryl-α-glycosides and 1,5-anhydro-2-C-aryl-2-deoxy alditols are described. The use of reliable, efficient phosphine-free Suzuki-Miyaura cross-coupling of 2-iodoglycals in aqueous media as a key step proceeds with complete regioselectivity at C-2 and enables access to 2-aryl-glycals with different configurations ...

A novel C5-alkylation of oxindoles using alcohols as alkylating agents under acid catalysis is described for the first time. The reactions of various benzylic, allylic and propargylic alcohols are studied to obtain the corresponding 5-substituted oxindoles in good yields.