Manganese oxide-loaded and -doped ceria as well as the corresponding barium-modified oxide catalysts were prepared for soot oxidation in the presence of NO(x), and were characterized by using X-ray diffraction, Brunauer-Emmett-Teller and NO temperature-programmed oxidation measurements. The activity of catalyst depended strongly on the NO2 production capacity, and the importance of surface nitr...

A technique of computing the pressure drop and deposition rate evolution during soot loading and the 3D distribution of deposited soot particles for micro-structured ceramic filter media is presented. Methods developed at Fraunhofer ITWM for generating 3D computer models representing the microstructure of the filter material and for computing soot particle deposition in the microstructure model...

Carbonaceous soot produced in a small diesel engine test facility was investigated with ultra-small-angle X-ray scattering. Three soot samples produced using a reference diesel fuel and the reference fuel plus two oxygenate additives were investigated. The presence of objects at three typical size ranges, i.e., aggregates, primary particles, and subunits, was observed. By studying soot powders ...

The scalar structure of the overfire (fuel-lean) region of sooting turbulent diffusion flames was investigated, considering ethylene and acetylene burning in air. Measurements and predictions are reported of the mean concentrations of major gas species and mean soot volume fractions. Predictions were based on the conserved-scaiar formalism in conjunction with the laminar flamelet approximation....

Soot concentrations are generally over predicted during the typical application of fire models. The addition of soot deposition and gravitational settling mechanisms to Fire Dynamics Simulator (FDS) results in improved predictions; however, those predictions are highly dependent upon assumptions of soot particle size. Large particle sizes appear to be needed to get FDS predictions on soot conce...

The cryptomelane catalysts containing transition metal (M/K-OMS-2, M = Cu, Ni, Co, Cr and Fe) was synthesized characterized by XRD, TEM/EDX, XRF, XPS, Raman, H2-TPR corroborated potassium thermal desorption measurements. were tested for soot oxidation in tight loose contact modes various conditions: O2, O2 + NO, SO2, NO SO2. alterations the activity discussed terms of manganese average number, ...

The development of a cascaded feedback control strategy for a vapor-phase axial deposition (VAD) process is investigated in this paper. VAD is a widely used process in the creation of high purity glass for optical fiber. In previous work a soot tip surface temperature controller was developed for the VAD process to reduce the effects of core soot temperature variation on deposition, leading to ...

In this work we present a numerical iterative procedure for the evaluation of the effect of signal absorption in two-color laser-induced incandescence (2C-LII) measurements. The correction process is applied to experimental results, previously published by our group, in an axisymmetric diffusion flame. We have studied the influence of signal trapping on peak soot temperature and on soot volume ...

The formation characteristics of aerosol particles from pulverized coal pyrolysis in high temperatures are studied experimentally. By conducting a drop-tube furnace, fuel pyrolysis processes in industrial furnaces are simulated in which three different reaction temperatures of 1000, 1200, and 1400 degrees C are considered. Experimental observations indicate that when the reaction temperature is...

The size distributions of nanoparticles in flames are measured using a novel particle mass spectrometer (PMS), which is developed for the size range between 0.3 and 50 nm and for number concentrations between 10(9) and 10(13). Using this instrument the particles are sampled without prior dilution from the flame into a molecular beam. The charged nanoparticles are then deflected by an electric f...