the acidity constants (pka) of thirty four (34) ;-substituted carboxylic acids in aqueous solution havebeen calculated using conductor-like polarizable continuum (c-pcm) solvation model. the gasphaseenergies at the density functional theory (dft-mpw1pw91) and solvation energies athartree fock (hf) are combined to estimate the pka values which are very close to the experimentalvalues where, and ...

Tthe Zografos–Balakrishnan-log-logistic (ZBLL) distribution is a new distribution of three parameters that has been introduced by Ramos et el. [1], and They presented some properties of the new distribution such as its probability density function, The cumulative distribution function, The  moment generating function, its hazard (failure) rate function, quantiles and moments, Rényi and Shannon ...

kahman is the most beneficial river in alashtar city for agriculture and aquiculture. as hydrology processes have random nature, statistics and probability are base of analysis of these processes and time series are used for this purpose. the first step in time series analysis includes parameters variation through time. second step is to stationary data, third is normalization and forth is mode...

The majority of hydraulic processes under a natural condition in a field are carried out under unsaturated flow conditions. The soil moisture retention curve (SMRC) is the most important hydraulic characteristic of an unsaturated soil whose knowledge is of prime importance in soil-water studies such as soil conservation, soil erosion, land evaluation, soil reclamation, and water resources manag...