N-Heterocyclic olefin (NHO)-based polymerization pathways for the copolymerization of ethylene oxide (EO) and propylene (PO) are investigated in detail. Employing situ 1H NMR spectroscopy, both an organocatalytic, anionic setup (system A) a zwitterionic, Lewis pair-type approach B) studied comparatively. The obtained kinetics data fitted to non-terminal model (Jaacks Ideal Integrated) terminal ...

PURPOSE Polycaprolactone (PCL) is a biodegradable polyester and has attracted attention as a suitable carrier for development of controlled drug delivery due to its non-toxicity and biocompatibility. It has been reported that the biodegradability of PCL can be enhanced by copolymerization with PEG. Molecular weight (Mw) and CL block lengths optimization in a series of synthesized PCEC copolymer...

Studies of the structural polymorphism exhibited by block copolymers in the presence of selective solvents are relatively recent, but very promising in terms of fundamental understanding and practical applications. Highlighting recent advances, this review progresses from ‘dry’ ordered ( ) copolymers to solvated ordered gel-like copolymers and ( ) lastly to solvated disordered but locally organ...

Supramolecular self-assembly of block copolymers in aqueous solution has received ever-increasing interest over the past few decades due to diverse biological and technological applications in drug delivery, imaging, sensing and catalysis. In addition to relative block lengths, molecular weights and solution conditions, chain architectures of block copolymers can also dramatically affect their ...

Geminal disubstitution on silicon in dialkylsilylene-spaced divinylarene copolymers may dictate the conformation and photophysical properties of the copolymers, bulky (i)Pr substituted copolymers being more folded than Me substituent analogues.

PURPOSE To evaluate surface properties of various intraocular lenses (IOLs), including a newly fabricated heparin-surface-modified (HSM) silicone IOL, with special reference to their efficiency in reducing potential silicone oil adherence to the IOL optics. SETTING Center for Research on Ocular Therapeutics and Biodevices, Department of Ophthalmology, Storm Eye Institute, Medical University o...

We perform Monte-Carlo simulations of a binary, strongly separated mixture of A- and B-type homopolymers with some amount of random AB copolymers added. The interface is analyzed and the interface tension is calculated using the model of capillary waves. We can clearly demonstrate that random copolymers are localized at real, fluctuating interfaces between incompatible polymer species and micel...

PURPOSE To determine the interaction of heavy silicone oil with various intraocular lens (IOL) materials and whether heavy silicone oil covers the silicone IOL optic as silicone oil does. SETTING Department of Ophthalmology, Dokuz Eylul University, Izmir, Turkey. METHODS The study group comprised 5 poly(methyl methacrylate) (PMMA) IOLs, 4 foldable silicone IOLs, 5 foldable hydrophilic acryl...