نتایج جستجو برای: silica supported catalysts

تعداد نتایج: 257434  

2012
Atsushi Ishihara Hiroyuki Nasu

Tetraethoxy orthosilicate (TEOS) was used not only as a precursor of silica, but also as an agent which reinforces the skeleton of silica-gel to prepare an aerogel and resultant silica and silica-alumina with large pore size and pore volume. In this gel skeletal reinforcement, the strength of silica aerogel skeleton was enhanced by aging with TEOS/2-propanol mixed solution to prevent the shrink...

Journal: :Science 2016
Sean T Hunt Maria Milina Ana C Alba-Rubio Christopher H Hendon James A Dumesic Yuriy Román-Leshkov

We demonstrated the self-assembly of transition metal carbide nanoparticles coated with atomically thin noble metal monolayers by carburizing mixtures of noble metal salts and transition metal oxides encapsulated in removable silica templates. This approach allows for control of the final core-shell architecture, including particle size, monolayer coverage, and heterometallic composition. Carbo...

Journal: :Chemistry 2008
Ken Motokura Mitsuru Tomita Mizuki Tada Yasuhiro Iwasawa

Acid-base bifunctional heterogeneous catalysts were prepared by the reaction of an acidic silica-alumina (SA) surface with silane-coupling reagents possessing amino functional groups. The obtained SA-supported amines (SA-NR2) were characterized by solid-state 13C and 29Si NMR spectroscopy, FT-IR spectroscopy, and elemental analysis. The solid-state NMR spectra revealed that the amines were immo...

2016
Victor Mougel Ka-Wing Chan Georges Siddiqi Kento Kawakita Haruki Nagae Hayato Tsurugi Kazushi Mashima Olga Safonova Christophe Copéret

Alkene metathesis is a widely and increasingly used reaction in academia and industry because of its efficiency in terms of atom economy and its wide applicability. This reaction is notably responsible for the production of several million tons of propene annually. Such industrial processes rely on inexpensive silica-supported tungsten oxide catalysts, which operate at high temperatures (>350 °...

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