Trypsin has been encapsulated in the mesopores of a hierarchical mesoporous silica material synthesized via Cu(I) catalyzed azide-alkyne click reaction between azide functionalized large spherical SBA-15 particles and alkyne functionalized mesoporous silica nanoparticles (MSNs). Encapsulated trypsin functions as an efficient biocatalyst and can be recycled several times.

A new bis(indenyl)zirconocene bearing a pendant Si-Cl anchor has been grafted onto MCM-41, SBA-15, MCM-48 and a disordered mesoporous silica for the polymerisation of ethylene and propylene, producing polymers with very high molecular weights, low polydispersities and, in the case of polypropylene, higher levels of isotacticity than obtainable with analogous homogeneous systems.

Ordered mesoporous silicas SBA-15 with high loadings of pendant vinyl groups have been synthesized via co-condensation of tetraethoxysilane (TEOS) and triethoxyvinylsilane (TEVS) templated with a triblock copolymer.

Two hybrid materials based on mesoporous silicas SBA-15 and MCM-41 functionalized with stable and electrically neutral Gd(iii) macrocyclic complexes were prepared, and their (1)H NMR relaxometric properties investigated as a function of temperature and magnetic field strength.

An inorganic-organic silica material (SBA-15-1), prepared by immobilization of the naphthalimide derivative within the channels of the mesoporous silica material SBA-15, is characterized by several spectroscopic methods. SBA-15-1 can be used as a chemical sensor for detecting and removing Hg(2+) in a heterogeneous system. The fluorescence enhancement of SBA-15-1 was attributed to the formation ...

Titanium dioxide (TiO2) is a safe inorganic ultraviolet (UV) filter with activity against UV damage. However, the recombination of carrier’s charge and tendency for TiO2 aggregation are main disadvantages. Substrate supports, such as mesoporous silica, biocompatible strategies to incorporate TiO2, altering its interaction skin. Since lips sensitive adversities environment, including radiation, ...

Nickel supported on SBA-15 doped with CeO2 catalysts (Ni-CeO2/SBA-15) was prepared, and used for steam reforming of toluene which was selected as a model compound of biomass gasification tar. A fixed-bed lab-scale set was designed and employed to evaluate the catalytic performances of the Ni-CeO2/SBA-15 catalysts. Experiments were performed to reveal the effects of several factors on the toluen...

While enzymes are valuable tools in many fields of biotechnology, they are fragile and must be protected against denaturing conditions such as unfavorable solution pH. Within living organisms, chaperonins help enzymes fold into their native shape and protect them from damage. Inspired by this natural solution, mesoporous silica SBA-15 with different pore diameters is synthesized as a support ma...