Hybrid organic / inorganic films, composed of poly 4-aminoquinolidine (PAQ) matrix and Prussian blue – like copper hexacyanoferrate (CuHCFe) redox centers were prepared. Platinum disk (Pt) was used as a conductive substrate onto which the hybrid films (Pt/PAQ/CuHCFe) were electrodeposited by potential cycling. Electrochemical behavior of the modified electrode was well characterized using cycli...

The interaction of DNA with quercetin was studied using scanning electrochemical microscopy and electrochemical impedance spectroscopy at glass carbon electrode. Information such as the surface coverage of the film and apparent rate constant of the redox active probe in solution was obtained. It is deduced that quercetin interacting with DNA forms a kind of electrochemical inactive supramolecul...

UNLABELLED We propose PEDOT PSS as a multi-functional composite material for an enhanced Li-air-battery air electrode. The PEDOT PSS layer was coated on the surface of carbon (graphene) using simple method. A electrode containing PEDOT PSS-coated graphene (PEDOT electrode) could be prepared without binder (such as PVDF) because of high adhesion of PEDOT PSS. PEDOT electrode presented co...

a carbon-paste electrode (cpe) chemically modified with the n-4,4'-azodianiline(ferrocenyl schiff base) complex and multi wall carbon nanotubes (adafcnte) was used as a highly sensitive electrochemical sensor for determination of trace amounts of atenolol. the oxidation peak potentials in cyclic voltammogram of adafcnte occurred around 550 mv vs ag/agcl (at ph 6.0) while this peak potentia...

Redox-active polymers with electrochemical reversibility and rapid electrode reaction rates are employed to develop organic electrode-active materials in batteries, based on their selfexchange reactions polymer layers. Negative charging of the electroneutral redox results a significant increase basicity allow protonation each redox-active site polymer. Since most hydrogenated products no longer...

A new hydroxylamine sensor has been fabricated by immobilizing oxadiazol denvative at the surface ol aglassy carbon electrode (GCE) modified by multi-wall carbon nanotube (MIVCNT). The adsorbed thin Illms oroxadiazol derivative on the MWCNT modified GCE show a pair of peaks with surface confined characierisnus.The oxadiazol derivative MWCNI (OMWCNT) modified GCE shows highly catalytic activity ...

“The performance of structured 3D electrode designs in a redox flow battery was compared to the conventional disordered carbon felt electrode. The presented electrodes were able achieve comparable potentials at pumping power that two three orders magnitude lower than electrode, allowing attain higher current densities same cost…“ Learn more about story behind research featured on front cover th...

For the modification of reversibility magnesium deposition–dissolution in non-aqueous glyme-based electrolytes, surface a metal or alloy AZ31 was covered by graphene oxide modified using Grignard reagent. After modification, chloride moieties appeared to connect with oxygen-containing functional groups oxide. The electrode MgCl-modified exhibited reversible redox reaction assigned from substanc...

As promising candidates for next-generation energy storage devices, aqueous rechargeable batteries are safer and cheaper than organic Li ion batteries. But due to the narrow voltage window of aqueous electrolytes, proper anode materials with low redox potential and high capacity are quite rare. In this work, bismuth electrode film was directly grown by a facile hydrothermal route and tested in ...

A glucose biosensor based on a nanocomposite made by layer-by-layer electrodeposition of the redox polymer into a multilayer containing glucose oxidase (GOx) and single-walled carbon nanotubes (SWCNT) on a screen-printed carbon electrode (SPCE) surface was developed. The objectives of the electrodeposition of redox polymer are to stabilize further the multilayer using a coordinative cross-linke...