As the level of human interaction with robotic systems increases, robot mobility becomes more important. Two wheeled robots offer higher levels of mobility and manoeuvrability when compared to their four wheeled counterparts with the ability to turn on the spot and easily negotiate tight corners. Whilst the stabilisation of two wheeled platforms has been well studied, there is no published rese...

ion has been found not to occur in the D + H20 reaction.22 Recently, the back reaction OH+D2 -HOD +D has been studied,12 and the HOD product shows pronounced back scattering, which is consistent with the proposed transition-state geometry. In addition to these investigations, two groups have reported experimental studies of the effect of vibrational excitation on the abstraction reaction. Crim ...

We present a combination of two techniques--QM/MM statistical simulation methods and QM/MM internal energy minimizations--to get a deeper insight into the reaction catalyzed by the enzyme chorismate mutase. Structures, internal energies and free energies, taken from the paths of the reaction in solution and in the enzyme have been analyzed in order to estimate the relative importance of the reo...

A kinetic model of the Boltzmann equation for chemical reactions without energy barrier is considered here with the aim of evaluating the reaction rate and characterizing the transport coefficient of shear viscosity for the reactive system. The Chapman-Enskog solution of the Boltzmann equation is used to compute the chemical reaction effects, in a flow regime for which the reaction process is c...

In the present study, an attempt has been made to synthesize 3-methyl-4-arylmethylene isoxazole-5(4H)-one derivatives through sonication of hydroxylamine hydrochloride, ethyl acetoacetate and benzaldehyde derivatives in the presence of imidazole as a novel and effective catalyst in aqueous media. This green reaction under ultrasound irradiation has advantageous compared to conventional...

The (p,t) transfer reaction is being studied for its potential use in surrogate reaction analyses. A theoretical model has been developed to predict spin-parity distributions of final states excited in the reaction. The model, after comparisons with experimental data, may provide a predictive capability to identify candidate isotopes for measurement. Preliminary results are presented for the Zr...

A new method for determination of the optimum temperature and activation energies based on an idea of the average rate of enzymatic reaction has been developed. A mathematical model describing the effect of temperature on a dimensionless activity for enzyme deactivation following the first-order kinetics has been derived. The necessary condition for existence of the function extreme of the opti...

Chemical reactions can be described by an energy diagram along a reaction coordinate in which an activation barrier limits the rate at which reactants can be transformed into products. This reaction impedance can be overcome by reducing the magnitude of the barrier through the use of catalysis, increasing the thermal energy of the system, or through macroscopic mechanical processes. Here, we de...