نتایج جستجو برای: pyrroles
تعداد نتایج: 1881 فیلتر نتایج به سال:
Multicomponent reactions are one of the most interesting concepts in modern synthetic chemistry and, as shown in this critical review, they provide an attractive entry into pyrrole derivatives, which are very important heterocycles from many points of view including medicinal and pharmaceutical chemistry and materials science (97 references).
The three-stage synthesis of a pyrrole analogue of chloramphenicol (5) was described. It is inactive.
Isotopic labelling studies were performed to probe a proposed 1,2-aryl shift in the gold-catalysed cycloisomerisation of alkynyl aziridines into 2,4-disubstituted pyrroles. Two isotopomers of the expected skeletal rearrangement product were identified using (13)C-labelling and led to a revised mechanism featuring two distinct skeletal rearrangements. The mechanistic proposal has been rationalis...
Enantiopure alkaloid mimics are synthesized via high yielding intramolecular cycloadditions of photogenerated azaxylylenes tethered to pyrroles, with further growth of molecular complexity via post-photochemical transformations of primary photoproducts. This expeditious access to structurally unprecedented polyheterocyclic cores is being developed in the context of diversity-oriented synthesis,...
Palladium-catalyzed amidation of five-membered heterocyclic bromides that contain multiple heteroatoms was achieved for the first time using the Pd/1 catalyst system. This system allows for efficient access to N-arylated imidazoles, pyrazoles, thiazoles, pyrroles, and thiophenes in moderate to excellent yield. Experimental results and DFT calculations point to the need for electron-rich and esp...
Herein, a novel and versatile method for the synthesis of N-heteroarylated dithieno[3,2-b:2,3’-d]pyrroles (DTP) is reported. By microwave-assisted Cu-catalyzed coupling parent H-DTP 1 with 5- 6-membered heteroaromatic halides variety N-functionalized DTPs was obtained. Supported by quantum chemical calculations X-ray structure analysis, structural optoelectronic properties π-conjugated systems ...
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