This work assesses the predictive power and capabilities of classical interatomic potentials for describing the atomistic structure of a fully inorganic water-oxidation catalyst in the gas phase and in solution. We address a Ru-polyoxometalate molecule (Ru-POM) that is presently one of the most promising catalysts for water oxidation due to its efficiency and stability under reaction conditions...

Alley cropping may promote greater sequestration of soil organic carbon. The objective of this study was to examine spatial variability of soil organic carbon (C) and nitrogen (N) fractions relative to tree rows in established alley cropping systems in north central Missouri. Soils were collected to a depth of 30 cm from two alley cropped sites, a 19-yr-old pecan (Carya illinoinensis)/bluegrass...

The paper investigates the relation between metaphoricity and distributional characteristics of verbs, introducing POM, a corpus-derived index that can be used to define the upper bound of metaphoricity of any expression in which a given verb occurs. The work moves from the observation that while some verbs can be used to create highly metaphoric expressions, others can not. We conjecture that ...

Unusually high photocatalytic activity of visible light-induced O₂ generation can be achieved by electrostatically-derived self-assembly between exfoliated Zn-Cr-LDH 2D nanosheets and POM 0D nanoclusters (W₇O₂₄⁶⁻ and V₁₀O₂₈⁶⁻) acting as an electron acceptor. This self-assembly can provide a high flexibility in the control of the chemical composition and pore structure of the resulting LDH-based...

Abstract When polyoxymethylene (POM)—a common polymer used in metal injection moulding feedstock—is exposed to heat and oxygen during compounding, it can be easily decomposed, releasing undesired gaseous formaldehyde products. In order reduce the emission from POM, amine treatment was performed. The effectiveness of propylamine at different concentrations its role as a scavenger studied via UV–...

Peat particulate organic matter (POM) has been hypothesized to act as a terminal electron acceptor (TEA) for anaerobic microbial respiration in northern peatlands, thereby lowering dissolved methane (CH4) concentrations these systems. However, the redox properties of peat POM and an assessment its state situ remain missing, mainly due lack accurate analytical approach quantify number electrons ...

Health-related outcomes often possess an intrinsic ordering but fail to meet the assumptions usually needed to perform an ordinary least-squares (OLS) regression. When the distribution of scores is highly non-normal, as occurs when the majority of respondents score at the very bottom or top of the scale, ordinal regression can be more valid, and sometimes more informative, than OLS regression. ...

A new photoresponsivemolecular polyanion in which two Fe(III) ions are simultaneously coordinated by two [A-a-PW9O34] 9 polyoxometalate units and two oxalato ligands has been obtained. When irradiated with UV light its potassium salt, 1, exhibits a remarkable photocoloration effect, attributable to the partial reduction of the POM units to give rise to a mixed-valence species. The photoinduced ...

Polyoxometalates (POMs) are discrete polynuclear metal-oxo anions with a fascinating variety of structures and unique chemical and physical properties. Their application in various fields is well covered in the literature, however little information about their usage in protein crystallization is available. This review summarizes the impact of the vast class of POMs on the formation of protein ...

Polyoxometalates (POMs) are, mostly anionic, metal oxide compounds that span a wide range of tunable physical and chemical features rendering them very interesting for biological purposes, an continuously emerging but little explored field. Due to their biological and biochemical effects, including antitumor, -viral and -bacterial properties, POMs and POM-based systems are considered as promisi...