Porous materials with photochromic units are currently under investigation as light allows for environmentally friendly and highly energy-efficient control gas separation storage, chemical sensing, drug delivery. In the application of photo-switching to CO 2 capture, researchers have tried endow a diversity porous such metal-organic frameworks organic polymers photo-responsive units. This revie...

The photochromic diarylethene derivative 1,2-bis(5-(4-ethynylphenyl)-2-methylthiophen-3-yl)perfluorocyclopentene (1) was submitted to photochemical, thermal stability and fatigue resistance studies in acetonitrile, also to evaluate its possible application as a new actinometer. This photochromic system covers a wide spectral absorption range, with intense bands in the UV and visible regions for...

The covalent attachment of synthetic photoswitches is a general approach to impart light sensitivity onto native receptors. It mimics the logic of natural photoreceptors and significantly expands the reach of optogenetics. Here we describe a novel photoswitch design-the photoswitchable orthogonal remotely tethered ligand (PORTL)-that combines the genetically encoded SNAP-tag with photochromic l...

We investigated the capability of molecular triads, consisting of two strong fluorophores that were covalently linked to a photochromic molecule, for optical gating. Therefore we monitored the fluorescence intensity of the fluorophores as a function of the isomeric state of the photoswitch. From the analysis of our data we develop a kinetic model that allows us to predict quantitatively the deg...

An overview of the recent advances in the state-of-the-art holographic recoding media dedicated to the dynamic holography display is presented in this paper. Unlike the traditional holographic media, those materials enable the holograms to be updatable rather than permanent like before. Over the past few years, a number of material recipes for this use have been disclosed and can be mainly divi...

A photochromic polymer exhibiting mechanochromic behavior is prepared by means of ring-opening polymerization (ROP) of epsilon-caprolactone by utilizing a difunctional indolinospiropyran as an initiator. The configuration of having the photochromic initiating species within the polymer backbone leads to a mechanochromic effect with deformation of polymer films leading to ring-opening of the spi...

Among many thermo-photochromic materials, the color-changing behavior caused by temperature and light is usually lack of a full color response. And the study on visible light-stimuli chromic response is rarely reported. Here, we proposed a strategy to design a thermo-photochromic chameleon biomimetic material consisting of photonic poly(N-isopropylacrylamide-co-methacrylic acid) copolymer and p...

Photochromic compounds are promising materials for optoelectronic and photonic applications because of their ability to undergo change in color under UV/Vis illumination due to reversible chemical transition from open to closed ring isomers (photocyclization). The by-produc formation may lead to irreversible photodegradation of the material, called fatigue. We use Density Functional Theory meth...

A series of novel dithienylethene-based macrocycles containing ammonium moieties has been synthesized. They have been employed as templates to construct [2]catenanes showing their photoisomerization properties by means of a dynamic covalent chemistry approach. Their structures have been reliably confirmed by NMR, ESI-MS or MALDI-QTOF-MS, and elemental analysis, and their energy-minimized struct...