Nanomaterials are vital to the realization of photoelectrochemical (PEC) sensing platform that provides sensitive detection and quantification low-abundance biological samples. Here, this work reports a Schottky junction-based BiOI/Ti3C2 heterostructure, used as photocathode for PEC bioanalysis. Specially, we realize in situ growth flower-like BiOI on 2D intrinsically negatively charged Ti3C2 M...