Data for the following three liquids are used for the analysis in Figs. 1-4 of the paper: tetramethyltetrahpenyl-trisiloxane (DC704), 5-polyphenyl-4-ether (5PPE), tripropylene glycol (TPG). In this supplementary we also include data for triphenyl phosphite (TPP), dibutyl phthalate (DBP), diethyl phthalate (DEP), and 2,3-epoxy propyl-phenyl-ether (2,3-epoxy). A summary of relevant information ab...

Highly efficient catalyst free methods for the synthesis of α-hydroxy-β-oxophosphonates and α-oxoesters have been described. The existence of a 2-oxo group in α-oxoaldehydes is a key factor in promoting the reaction of the tervalent phosphite form towards 2-oxoaldehydes in the synthesis of α-hydroxy-β-oxophosphonates. The in situ activated α-C-H atom of α-hydroxy-β-oxophosphonates sustains aero...

ionic liquids such as 1,3-dialkylimidazolium salts make excellent catalysts and solvents for synthesis of dialkyl 2-(dialkoxyphosphoryl)-3-(1-oxo-1-h-phthalazin-2-yl)succinates from 2h-phthalazin-1-one, dialkyl acetylenedicarboxylates, and trialkyl phosphites. under similar conditions, triphenyl phosphite led to dialkyl 2-(diphenoxyphosphoryl)-3-(1-oxo-1-h-phthalazin-2-yl)succinates. the ionic ...

The aim of this work is to probe the influence of nanoclay and turmeric spends content on microcrystalline of vinyl ester hybrid nanocomposites. A series of vinyl ester hybrid nanocomposites have been fabricated with varying amounts of TS viz., 0, 2.5, 5, 7.5 and 10 % w/w along with 2% nanoclay. The microcrystalline parameters such as crystallite size and lattice strain of vinyl ester hybrid na...

As a green material, used date pits oil is increasingly utilized as inexpensive feedstock for ethyl ester (biodiesel) production. Waste date pits as a raw material are one of the highly produced agricultural wastes in Iran. This study investigated the effect of several procedure parameters including the ethanol/oil molar ratio, reaction temperature and amount of catalysts on the yield of the pr...

We have previously performed empirical valence bond calculations of the kinetic activation barriers, Δ G‡calc, for the deprotonation of complexes between TIM and the whole substrate glyceraldehyde-3-phosphate (GAP, Kulkarni et al. J. Am. Chem. Soc. 2017 , 139 , 10514 - 10525 ). We now extend this work to also study the deprotonation of the substrate pieces glycolaldehyde (GA) and GA·HPi [HPi = ...