نتایج جستجو برای: ph electrode
تعداد نتایج: 228520 فیلتر نتایج به سال:
• Caldwell* was the first to measure directly the pH of large cells (crab muscle fibres) with a glass electrode. Kostyuk and Sorokina reduced considerably the dimensions of the glass electrode and measured directly the intracellular pH of sartorius muscle (frog). Finally, Carter first measured the intracellular pH of a mammalian cell (rat voluntary muscle) by means of a double-barreled microele...
A carbon Paste electrode modified with cobalt (II) phthalocyanine (CoPC) was used as a sensitive potentiometric sensor for determination of ascorbic acid in aqueous solutions. The potential response of the electrode is a linear function of ascorbic acid concentration over the range 5 10 to 10 M (?1- 1800 µg ML ) with a Nernstian slope of 56 mV at pH 7. The limit of detection was 0.2 µg ...
Coimmobilization of beta-galactosidase and glucose oxidase in a redox polymer, polyvinylferrocenium perchlorate (PVF+ ClO4-), led to the development of an enzyme electrode for the determination of lactose. The amperometric response of the electrode was measured at +0.70 V vs. SCE, which was due to the electrooxidation of enzymatically produced H2O2. The effects of the substrate and buffer conce...
a flow injection method is reported for the determination of ascorbic acid based on amperometric detection, using a cobalt(ii) phthalocyanine (copc) modified graphite-epoxy electrode. the amperometric respons was evaluated with regard to ph, ionic strength of the electrolyte, flow rate of the carrier solution, injected sample volume and conditioning time of the electrode. the limit of detection...
A stopped flow rapid reaction apparatus capable of following changes of +/-0.02 pH unit in 0.1 ml of solution in less than 0.005 sec has been developed, utilizing a commercially available pH-sensitive glass electrode. Using this instrument, extracellular pH at 37 degrees C was followed from less than 0.025 sec to 300 sec after mixing equal volumes of the following CO(2)-free solutions: (A) norm...
The ability to accurately measure real-time pH fluctuations in-vivo could be highly advantageous. Early detection and potential prevention of bacteria colonization of surgical implants can be accomplished by monitoring associated acidosis. However, conventional glass membrane or ion-selective field-effect transistor (ISFET) pH sensing technologies both require a reference electrode which may su...
The effects of solution pH and anion adsorption for the formic acid oxidation reaction on the Pt(111) electrode have been examined using electrochemical techniques. Regarding the pH effects, it has been found that oxidation currents for this reaction increases as the pH increases, which indicates that solution formate is involved in the reaction mechanism. Unexpectedly, the adsorption of sulfat...
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