This study investigates for the first time the relative importance of dissolved organic carbon (DOC) and particulate organic carbon (POC) in the fluvial carbon flux from an actively eroding peatland catchment in the southern Pennines, UK. Event scale variability in DOC and POC was examined and the annual flux of fluvial organic carbon was estimated for the catchment. At the event scale, both DO...

We have investigated the seasonal cycle of nutrients, chlorophyll a, dissolved organic nitrogen (DON), and dissolved and particulate organic carbon (DOC and POC) for 10 stations in the Belgian coastal zone. Special attention was given to phosphorus speciation, i.e. dissolved inorganic and organic phosphorus (DIP and DOP) and particulate inorganic and organic phosphorus (PIP and POP). Spatial an...

The main function of heterotrophic bacterioplankton in marine carbon cycling is the conversion of dissolved organic carbon (DOC) into biomass and CO2. The relative importance of bacterial biomass production (BP) versus respiration (BR) is expressed by the bacterial growth efficiency (BGE = BP/(BP + BR) × 100). Studies on the dynamics of the BGE of bacterioplankton growing on natural DOC coverin...

The interconversion of carbon in organic, inorganic and refractory carbon is still beyond the grasp of present environmentalists. The bacteria and their phages being the most abundant constituents of the aquatic environment, represents an ideal model for studing carbon regulation in aquatic system. The refractory dissolved organic carbon (DOC) a recently coined terminology from the microbe-driv...

Metal-free deprotonative functionalization of heteroaromatic compounds was achieved using an organic superbase catalyst; an organosilicon additive such as trimethylsilylpropyne was employed for activating the catalytic cycle of 1,2-addition to carbonyl compounds.

UNLABELLED Hydrogen gas (H(2)) is a possible future transportation fuel that can be produced by anoxygenic phototrophic bacteria via nitrogenase. The electrons for H(2) are usually derived from organic compounds. Thus, one would expect more H(2) to be produced when anoxygenic phototrophs are supplied with increasingly reduced (electron-rich) organic compounds. However, the H(2) yield does not a...

Long-term secular variation in the isotopic composition of seawater fixed nitrogen (N) is poorly known. Here, we document variation in the N-isotopic composition of marine sediments (δNsed) since 660 Ma (million years ago) in order to understand major changes in the marine N cycle through time and their relationship to first-order climate variation. During the Phanerozoic, greenhouse climate mo...

Methanotrophs are a group of phylogenetically diverse microorganisms characterized by their ability to utilize methane as their sole source of carbon and energy. Early studies suggested that growth on methane could be stimulated with the addition of some small organic acids, but initial efforts to find facultative methanotrophs, i.e., methanotrophs able to utilize compounds with carbon-carbon b...