Abstract The angular momentum Jinc of a light beam can be changed by passage through a slab of crystal. When the beam is incident along the optic axis of a biaxial crystal, which may also possess optical activity (chirality), the final angular momentum J can have both orbital (Jorb) and spin (Jsp) contributions, which we calculate paraxially exactly for arbitrary biaxiality and chirality and in...

The electroclinic (EC) effect is the tilt of the optical axis of a liquid crystal in the plane perpendicular to an applied electric field. Chirality plays a key role for its emergence. Based on the molecular and phase symmetry we derive a molecular expression for the EC coefficient, the material property that quantifies the linear coupling between tilt and electric field, in nematic liquid crys...

W ithin the last years optically active oxazoline ligands have proven use in transition-metal catal­ ysed asymmetric synthesis. In copper-catalysed cy­ clopropanation reactions oxazolines turned out to be the ligands of choice [2, 3], Oxazolines substituted in 2-position with a heteroaromatic com pound such as pyridine [4] gave good results in many systems of asymmetric catalysis, e. g., in ena...

The nucleosome, the fundamental packing unit of chromatin, has a distinct chirality: 147 bp of DNA are wrapped around the core histones in a left-handed, negative superhelix. It has been suggested that this chirality has functional significance, particularly in the context of the cellular processes that generate DNA supercoiling, such as transcription and replication. However, the impact of tor...

We show that negative refraction with minimal absorption can be obtained by means of quantum interference effects similar to electromagnetically induced transparency (EIT). Coupling a magnetic dipole transition coherently with an electric dipole transition leads to electromagnetically induced chirality, which can provide negative refraction without requiring negative permeability and also suppr...

When a linear chain of plasmonic nanoparticles is subject to longitudinal magnetic field, it exhibits optical Faraday rotation. If the magnetized nanoparticles are plasmonic ellipsoids arranged as a spiral chain, the interplay between the Faraday rotation and the geometrical spiral rotation (structural chirality) can strongly enhance nonreciprocity. This interplay forms a waveguide that permits...

We present differential optical reflectivity and null transmission ellipsometry data from several mixtures of MHPBC enantiomers. From this data, we have determined the chiral smectic phase sequence as a function of enantiomeric excess. The data suggest a change in the structure of the smectic-C(*)(alpha) phase and the surface tilt state as the enantiomeric excess is reduced. The results also sh...

We demonstrate experimentally that localized emission states in coupled broad-area semiconductor lasers can carry a finite orbital angular momentum. The resulting structures therefore possess the chirality of optical vortices together with the properties of localized structures in dissipative systems, namely, the coexistence with a low intensity homogeneous emission and the mutual independence....

Controlled mirror symmetry breaking arising from chemical and physical origin is currently one of the hottest issues in the field of supramolecular chirality. The dynamic twisting abilities of solvent molecules are often ignored and unknown, although the targeted molecules and polymers in a fluid solution are surrounded by solvent molecules. We should pay more attention to the facts that mostly...

The chirality-dependent asymmetric light-matter interaction can be enhanced using various artificial photonic structures as well engineered incident field. Compared with chiral structures, the optical field is less explored and recently recognized a new regime in tailoring interaction. In this work, we demonstrate that weakly spheres exhibit maximum scattering circular dichroism (CD) by to cons...