The modified Claus process is the major technology for the recovery of elemental sulfur from hydrogen sulfide. The chemical reactions that can occur in the reaction furnace are numerous and many byproducts such as carbon disulfide and carbon carbonyl sulfide are produced. These compounds can often contribute from 20 to 50% of the pollutants and therefore, should be hydrolyzed in the catalytic c...

We investigate mortar multiscale numerical methods for coupled Stokes and Darcy flows with the Beavers–Joseph–Saffman interface condition. The domain is decomposed into a series of subdomains (coarse grid) of either Stokes or Darcy type. The subdomains are discretized by appropriate Stokes or Darcy finite elements. The solution is resolved locally (in each coarse element) on a fine scale, allow...

The magnesium–sulfur (Mg-S) battery has attracted considerable attention as a candidate of post-lithium systems owing to its high volumetric energy density, safety, and cost effectiveness. However, the known shuttle effect soluble polysulfides during charge discharge leads rapid capacity fade hinders realization sulfur-based technology. Along with approaches for cathode design electrolyte formu...

The X-ray absorption spectroscopy technique has been applied to study different stages of the lithium/sulfur (Li/S) cell life cycle. We have investigated how speciation of S in Li/S cathodes changes upon the introduction of CTAB (cetyltrimethylammonium bromide, CH₃(CH₂)15N⁺(CH₃)₃Br-) and with charge/discharge cycling. The introduction of CTAB changes the synthesis reaction pathway dramatically ...

The toxic effects of sulfur mustard have been attributed to DNA modification with the formation of 7-hydroxyethylthioethyl guanine, 3-hydroxyethylthioethyl adenine and the cross-link, di-(2-guanin-7-yl-ethyl)sulfide. To investigate the action of bacterial 3-methyladenine DNA glycosylase II (Gly II) on these adducts, calf thymus DNA was modified with [14C]sulfur mustard and used as a substrate f...

The asphalt paver must fulfill a set of basic requirements, from sufficient bearing capacity for the expected loads, stability and good resistance to deformations resulting passage large loads at high temperatures, also securing an impermeable surface that achieves adequate drainage water. Hence, it is necessary search permanently continuously improved materials are resistant influence factors ...

To find out which render mortar mix shows the best durability properties, we have designed four ageing tests that aim to simulate water movements, ice formation and salt crystallization in lime mortars exposed to an extreme, but realistic, range of temperature and humidity. It has been found that the response of individual mortar mixes differs according to the mechanism and the agent of attack....

Hierarchical a posteriori error estimators are introduced and analyzed for mortar nite element methods. A weak continuity condition at the interfaces is enforced by means of Lagrange multipliers. The two proposed error estimators are based on a defect correction in higher order nite element spaces and an adequate hierarchical two-level splitting. The rst provides upper and lower bounds for the ...