a simple ion imprinted amino-functionalized sorbent was synthesized by coupling activated carbon with iminodiacetic acid, a functional compound for metal chelating, through cyanoric chloride spacer. the resulting sorbent has been characterized using fourier transform infrared spectroscopy (ft-ir), elemental analysis, thermogravimetric analysis (tga) and evaluated for the preconcentration and de...

heavy metal contamination in the environment could cause harmful effects both to human health and aquatic life. numerous remediation methods had been developed to encounter with the contamination problem prior to degrade, decrease and to purify the contaminated water at minimal concentration as low as possible. therefore, in current study, commercialized chicken eggshells and hybrid akar putra ...

In biosciences and biotechnology, the expanding application of physicochemical approaches using modern instrumental techniques is an efficient strategy to obtain valuable and often unique information at the molecular level. In this work, we applied a combination of vibrational (Fourier transform infrared (FTIR), FT-Raman) spectroscopic techniques, useful in overall structural and compositional ...

Fluorescence resonance energy transfer (FRET) has been used to study the global folding of an uranyl (UO(2)(2+))-specific 39E DNAzyme in the presence of Mg(2+), Zn(2+), Pb(2+), or UO(2)(2+). At pH 5.5 and physiological ionic strength (100 mM Na(+)), two of the three stems in this DNAzyme folded into a compact structure in the presence of Mg(2+) or Zn(2+). However, no folding occurred in the pre...

The chemistry, electronic structure, and electron injection characteristics at interfaces formed between tris~8-hydroxy quinoline! aluminum (Alq3) and magnesium ~Mg! and aluminum ~Al! are studied via x-ray photoemission spectroscopy, ultraviolet photoemission spectroscopy, and current– voltage (I – V) measurements. Both metal-on-Alq3 and Alq3-on-metal interfaces are investigated. All interfaces...

the disposed wastes of zinc industries contain large amounts of heavy metals such as pb2+ and cd2+. these elements are considered as hazardous elements to human beings and other organisms. this study aims at introducing the fungal isolates that evolved to be compatible with waste deposits during the time and can absorb pb2+ and cd2+ions. during the spring and autumn in 2011, eight samples of se...

Nickel (Ni) and magnesium (Mg) exert separate and interacting effects on cells: Ni is toxic while Mg enhances the transformation response of transformed cells and protects from heavy metal-induced toxicity. Transformed rat liver epithelial cells were used in the soft agar (SA) assay to measure the effect of Ni and/or Mg on the expression of anchorage independence. Cells were exposed to +/- Ni a...

classical xerogels are robust, inexpensive and nontoxic materials with low-ordered nanoporous structures. in water streams where the ph is higher than the point of zero charge, the surface of classical xerogels such as tetraethoxy orthosilan (teos) xerogel is negatively charged. it was assumed that a xerogel can work as a strong adsorbent for metal ions without further modification. therefore, ...