نتایج جستجو برای: methyl acetoacetate

تعداد نتایج: 111325  

Journal: :Inorganic chemistry 2002
José S Casas María V Castaño Eduardo E Castellano Javier Ellena María S García-Tasende Angeles Gato Agustín Sánchez Luisa M Sanjuán José Sordo

The reactions of Zn(OAc)(2) with acetoacetanilide, methyl acetoacetate, o-acetoacetanisidide, and ethyl 2-methylacetoacetate thiosemicarbazones (HTSC(1), HTSC(2), HTSC(3), and HTSC(4), respectively) were explored in methanol. With HTSC(1), HTSC(2), and HTSC(3), following isolation of the corresponding zinc(II) thiosemicarbazonates [Zn(TSC(x))(2)] (x = 1, 2, 3), the mother liquors afforded pyraz...

Journal: :Gut 1996
W E Roediger W Babidge S Millard

BACKGROUND Bacterial production of anionic sulphide is increased in the colon of ulcerative colitis and sulphides can cause metabolic damage to colonocytes. AIMS To assess the reversal of the damaging effect of sulphide to isolated colonocytes by methionine and methionine derivatives. METHODS AND SUBJECTS Isolated colonocytes were prepared from rat colons and 12 human colectomy specimens. I...

2003
KONRAD BLOCH

Cholesterol, which is formed by biological synthesis, contains angular methyl groups and branched side chains. A few other tissue constituents exist which contain branched chains, notably valine and leucine, but these are all essential dietary constituents. It has been shown (1) that acetic acid participates in the synthesis of the entire structure of cholesterol, but no obvious mechanism is kn...

Journal: :Molecules 2006
Kwang-Chan Ahn Jae-Chul Jung Oee-Sook Park

A convenient synthesis of 3,11-dimethylnonacosan-2-one (1) is described. Our strategy involves the use of well known C-alkylation and ethyl acetoacetate synthesis reactions as key steps. We expect that this method will prove to be useful for large scale preparation of 1 and modification of dimethylnonacosanones.

Journal: :Journal of Biological Chemistry 1963

Journal: :Journal of Biological Chemistry 1948

Journal: :The Journal of the Society of Chemical Industry, Japan 1971

Journal: :Journal of Biological Chemistry 1970

Journal: :The Journal of clinical investigation 1973
O E Owen G A Reichard H Markus G Boden M A Mozzoli C R Shuman

The metabolic and kinetic responses to rapidly intravenously administered sodium acetoacetate (1.0 mmol/kg body wt) was studied after an overnight fast in 12 male and female adults weighing between 88 and 215% of average body weight. Blood was obtained before, during, and after the infusion for determination of circulating concentrations of immunoreactive insulin, glucose, acetoacetate, beta-hy...

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