Heavy metals are potentially toxic to human life and the environment. Metal toxicity depends on chemical associations in soils. For this reason, determining the chemical form of a metal in soils is important to evaluate its mobility and hioavailability . Sequential extraction was used to fractionate four heavy metals (Cd, Cu, Ni, and Zn) from nine contaminated soils into six operationally defin...

1. Abstract We have successfully engineered n-type and p-type metal electrodes with the correct work functions on high-K gate dielectrics for high-performance CMOS applications. The resulting metal gate/high-K dielectric stacks have i) equivalent oxide thickness (EOT) of 1.0nm with negligible gate oxide leakage, ii) desirable transistor threshold voltages for n-and p-channel MOSFETs, and iii) t...

Two-dimensional semiconductors, such as transition-metal dichalcogenides (TMDs) and black phosphorous (BP), have found various potential applications in electronic and opto-electronic devices. However, several problems including low carrier mobility and low photoluminescence efficiencies still limit the performance of these devices. Interfacing 2D semiconductors with functional oxides provides ...

In contrast with Mobility Factor (MF) and Risk Assessment Code (RAC) indices, IR attributes a risk share to metal species bound to reducible and oxidizable phases which are totally neglected in both of the two above-mentioned indices. In other words, besides the absolutely mobile fractions, the potentially mobile ones are also regarded in risk evaluation process elaborated by IR. The different ...

The structure of inositol monophosphatase has been determined to 2.60 A resolution in complexes with Mn2+ and with Mn2+ and phosphate. In the Mn2+ complex, three metal cations and one Cl were bound in the active site on each of the two subunits of the enzyme. Ligands to the three metals include the side chains of Glu 70, Asp 90, Asp 93, and Asp 220, t he carbonyl group of Ile 92, several solven...

We investigate the electronic characteristics and the absorption spectra of poly(3-octylthiophene), POT, films grown by electrochemical methods onto Au substrates. We discuss the results considering the morphological factor. POT films thickness can be controlled by current density in the electropolymerization process. The film roughness depends on the thickness, being about 12% of film thicknes...

Mixture experimental design was used to enhance the separation selectivity of metal ions in nonaqueous capillary electrophoresis. The separation of cations (Ag, Fe, Cr, Mn, Cd, Co, Pb, Ni, Zn and Cu) was achieved using imidazole as UV co-ion for indirect detection. Acetic acid was chosen as an electrolyte because its cathodic electroosmotic flow permits faster separation. The composition of org...

Understanding the roles of disorder and metal/graphene interface on the electronic and transport properties of graphene-based systems is crucial for a consistent analysis of the data deriving from experimental measurements. The present work is devoted to the detailed study of graphene nanoribbon systems by means of self-consistent quantum transport calculations. The computational formalism is b...