Electrospray ionization (ESI) on mixtures of acidic fibrinopeptide B and two peptide analogs with trivalent lanthanide salts generates [M + Met + H](4+), [M + Met](3+), and [M + Met -H](2+), where M = peptide and Met = metal (except radioactive promethium). These ions undergo extensive and highly efficient electron transfer dissociation (ETD) to form metallated and non-metallated c- and z-ions....

Metal tolerance proteins (MTPs) are a gene family of cation efflux transporters that occur widely in plants and might serve an essential role in metal homeostasis and tolerance. Our research describes the identification, characterization, and localization of OsMTP11, a member of the MTP family from rice. OsMTP11 was expressed constitutively and universally in different tissues in rice plant. He...

The volume transition induced by monovalent-divalent cation exchange of fully neutralized polyacrylate hydrogels was investigated in aqueous NaCl solutions. The variation of the osmotic swelling pressure, shear modulus, and mixing pressure was measured when Na(+) ions were substituted by divalent or trivalent cations. Alkali metal salts move freely throughout the entirely network, and alkaline ...

Macropolycyclic ligands containing appropriate binding sites and cavities of suitable size and shape, may be designed so as to display molecular recognition in the formation of selective inclusion complexes, cryptates, with metal cations, but also with anions and molecules. Macrobicyclic ligands B form highly stable and selective alkali and alkaline-earth cryptates, displaying a pronounced cryp...

The M-box riboswitch couples intracellular magnesium levels to expression of bacterial metal transport genes. Structural analyses on other riboswitch RNA classes, which typically respond to a small organic metabolite, have revealed that ligand recognition occurs through a combination of base-stacking, electrostatic, and hydrogen-bonding interactions. In contrast, the M-box RNA triggers a change...

METAL CHALCOGENIDE NANOPARTICLE GEL NETWORKS: THEIRFROMATION MECHANISM AND APPLICATION FOR NOVEL MATERIALGENERATION AND HEAVY METAL REMEDIATION VIA CATIONEXCHANGE REACTIONSby IRINA R. PALAMay 2012Advisor: Dr. Stephanie L. BrockMajor: ChemistryDegree: Doctor of PhilosophyThe dissertation research is focused on (1) uncovering the mechanism of metalchalc...

The absorption of metal ions in the mammalian single-stomached gut is fortunately highly selective, and both luminal and tissue regulation occur. Initially, assimilation of metal ions in an available form is facilitated by the intestinal secretions, chiefly soluble mucus (mucin) that retards hydrolysis of ions such as Cu, Fe and Zn. Metal ions then bind and traverse the mucosally-adherent mucus...

This study illustrates the complimentary nature of selected techniques for characterizing kaolinite. For the particular type of kaolinte studied, scanning electron micrographs revealed the presence of crystallites and mostly larger than clay-sized particles. These findings were in agreement with the low cation exchange capacity, low specific surface area, low zero point of charge and high purit...

Abstract Considering the importance of sub-monolayer transition metal oxides supported on another oxide in many industrial processes, with help a DFT + U approach, we provide information structural and electronic properties pure M 2 O 3 mixed MM ′O monolayers ( , ′ = Ti, V, Cr, Fe) an α -Al (0001) support. With their structure prolongation alumina corundum lattice, have non-equivalent surface i...

Leucites are tetrahedrally coordinated silicate framework structures with some of the silicon cations partially replaced by divalent or trivalent cations. These have general formulae A 2 B Si 5 O 12 and AC 6 ; where is a monovalent alkali metal cation, C cation. In this paper, we report Rietveld refinements three more synthetic leucite analogues stoichiometries Cs NiSi , RbGaSi CsGaSi . Ia $\ba...