a selective and sensitive method for determination of cadmium and zinc is presented. the method is based on adsorptive accumulation of the complexes of cd (ii) and zn (ii) ions with 4-amiono-5-methyl-2,4-dihydro-3h-1,2,4-triazol-3-tion (mmtt) onto hanging mercury drop electrode (hmde), followed by reduction of the adsorbed species by voltammetric scan using differential pulse modulation. the li...

The present work describes a selective, rapid and sensitive method for the determination of cobalt using the adsorptive differential pulse voltammetry technique. The method is based on the accumulation of Co(II) complex with 2-aminocyclopentene-1-dithiocarboxylic acid on a hanging mercury drop electrode, followed by measurement of the current of the adsorbed complex. The effects of experimental...

the present investigation attempted to develop the ceramic adsorbent media in order to remove the mercury from aqueous phase. two ceramics, akadama volcanic ash soil-ceramic (aceramic) and improved magnesium oxide impregnated akadama volcanic ash soil-ceramic (maceramic) were produced from raw akadama volcanic ash soil by heating process to determine the hg(ii) adsorption capacity. adsorption e...

Both groundwater flow and mercury concentrations in pore water and seawater were quantified in the groundwater seeping site of the Bay of Puck, southern Baltic Sea. Total dissolved mercury (HgTD) in pore water ranged from 0.51 to 4.90 ng l-1. Seawater samples were characterized by elevated HgTD concentrations, ranging from 4.41 to 6.37 ng l-1, while HgTD concentrations in groundwater samples ra...

Mercury is a potent neurotoxin for humans, particularly if the metal is in the form of methylmercury. Mercury is widely distributed in aquatic ecosystems as a result of anthropogenic activities and natural earth processes. A first step toward bioaccumulation of methylmercury in aquatic food webs is the methylation of inorganic forms of the metal, a process that is primarily mediated by anaerobi...

Dibutyl-Disulfide Montmorillonite (DD-MMT) was synthesized successfully and found to bean excellent adsorbent for Hg(II) removal. The fourier transform infrared spectroscopy (FTIR),x-ray diffraction spectrum (XRD) and scanning electron microscopy (SEM) were used tocharacterize properties of the absorbent. The effects of several parameters such as solutionpH, adsorbent dose, contact time and the...

Concentrations of total Hg, Hg (II), and methylmercury were measured in stream-sediment, stream-water, and fish collected downstream from abandoned mercury mines in southwestern Alaska to evaluate environmental effects to surrounding ecosystems. These mines are found in a broad belt covering several tens of thousands of square kilometers, primarily in the Kuskokwim River basin. Mercury ore is d...