In this study, the crystallization behavior of a 65GeO2-15PbO-10MgF2-10MgO glass (prepared by the conventional melt quenching technique) has been investigated. The microstructure and crystallization behaviors of this glass were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), non-isothermal differential thermal analysis (DTA) and Fourier transform infrared spectr...

For a Czochralski growth of Ge crystal, thermal fields have been analysed numerically using the three-dimensional finite volume method (FLUENT package). The arrangement used in a real Czochralski crystal growth lab included a graphite crucible, heat shield, heating device, thermal insulation and chamber including two gas outlets. We have considered two cases for calculations, which are configur...

melting. This too can be demonstrated both by MELTS calculations We present a rigorous calculation of the isobaric entropy (S) change and by calculations in simple model systems. Productivities for of the melting reaction for peridotite (∂S/∂F ) P , where F is the systems enriched in incompatible components are systematically melt fraction. Calculations at 1 and 2 GPa for fertile and depleted l...

In this work, rheological properties of poly(lactic acid) (PLA), low density polyethylene (LDPE) polymer blends were investigated in the molten state. The experiments were carried on a capillary rheometer. The effect of shear stress, temperature and blending ratio on the flow activation energy at a constant shear stress and melt viscosity of the blends are described. The results showed that the...

We report a comparison of high resolution inelastic x-ray Brillouin scattering to coherent inelastic neutron scattering for amorphous deuterated polybutadiene, done for one temperature in the glass phase and another one in the melt. The x-ray scattering proves to be by far the better technique for such a polymer within its present resolution bounds. The neutron scattering allows one to extend t...

By application of optical coherence tomography (OCT), an interferometric noncontact imaging technique, the crystallization of a supercooled poly(propylene) melt in a slit die is monitored. Both the quiescent and the sheared melt are investigated, with a focus on experiments where solidification and flow occur simultaneously. OCT is found to be an excellent tool for that purpose since the result...

The influence of the morphology of industrial graphite nanoplate (GNP) materials on their dispersion in polycarbonate (PC) is studied. Three GNP morphology types were identified, namely lamellar, fragmented or compact structure. The dispersion evolution of all GNP types in PC is similar with varying melt temperature, screw speed, or mixing time during melt mixing. Increased shear stress reduces...

The crystallization of undercooled Pd43Ni10Cu27P20 melts is studied under isothermal conditions and at constant heating and cooling rates. Investigations are carried out by fluxing the melt with B2O3 and without any fluxing material. The isothermal experiments allow us to determine the complete time–temperature-transformation diagram with a minimum crystallization time of about 200 s for the fl...

Polycarbonate foams reinforced with 0,5 wt% of graphene were obtained by firstly melt-mixing the polycarbonate and graphene in an internal mixer, compression-moulding the melt-compounded grinded material and lastly dissolving CO2 inside a high pressure vessel. The CO2 desorption behaviour in the unfilled polycarbonate and nanocomposite was studied in terms of the CO2 saturation concentration an...

Defects during Plasma Transfer Arc (PTA) beam fusion additive manufacturing (AM) processing of Ti-6Al-4V, including lack of fusion, porosity variations, and solidification cracking, have been monitored using near infrared (1.62 μm) imagery at 300 Hz, 300 μm spatial resolution and melt pool sizes of greater than 12μ. The temperature evolution exhibits a periodic temperature modulation of more th...