A novel and easily accessible luminescent iridium(iii) complex [Ir(tpy)2(N^N)]PF6 (, tpy = 2-(p-tolyl)pyridine, N^N = 4-[(4-amino-3-nitrophenoxy)-methylene]-4'-methyl-2,2'-bipyridine) for the sensing of HOCl has been designed and synthesized. The detection strategy is based on the HOCl-promoted cleavage of the PET quenching 4-amino-3-nitrophenyloxy moiety of the weakly emissive complex , which ...

A general methodology is presented for in situ detection of cavitation impact phenomena on structures based on inverse analysis of luminescent emissions resulting from the collapsing of bubbles onto surfaces. Following an inverse-analysis approach, luminescent emission signatures are correlated with the general structure of asymmetric bubble collapse onto a surface. This method suggests applica...

This paper reports the synthesis, characterization, photophysical and structural properties of the homologous series of good emitting pentacoordinated GaQ'2L complexes 1-3, where Q' is 2-methyl-quinolin-8-olate and L is a phenolate substituted in para position with respect to the oxygen donor atom. A combined approach between the experimental structural analysis (i.e. the molecular fragments in...

The ability to synthesize upconversion nanocrystals (UCNCs) with tailored upconversion luminescence and controlled size is of great importance for biophotonic applications. However, until now, limited success has been met to prepare bright, ultrasmall, and monodispersed β-NaYF₄:Yb3+/Er3+ UCNCs. In this work, we report on a synthetic method to produce monodisperse hexagonal NaYF₄:Yb3+/Er3+ nanoc...

original article background and objectives: one type of electromagnetic fields, based on frequency range, is extremely low frequency (elf) fields. there are lots of reports about measuring elf- magnetic field (mf) in substations, power plants, cities, near high voltage power lines and etc. this study aimed to compare the difference between measurement of three-axis and single-axis probe mf mete...

The use of the water-oil interface provides significant advantages in the synthesis of inorganic nanostructures. Employing the water-toluene interface, luminescent CdS nanocrystals have been obtained at a relatively modest temperature of 35 degrees C. The diameters of the particulates can be varied between 1.0 and 5.0 nm. In addition, we have devised a new method for transferring thin films at ...

Luminescent ruthenium(II)-cyanide complex with N-heterocyclic carbene pincer ligand C(∧)N(∧)C = 2,6-bis(1-butylimidazol-2-ylidene)pyridine and 2,2'-bipyridine (bpy) shows minimal cytotoxicity to both human breast carcinoma cell (MCF-7) and human retinal pigmented epithelium cell (RPE) in a wide range of concentration (0.1-500 μM), and can be used for the luminescent imaging of endocytosis of th...

CdSe nanocrystals in solution and films can enter a metastable state in which the highly luminescent nanocrystals become dark. This change, which we attribute to a surface transformation, can be caused by heating or by changing the environment of the nanocrystals at room temperature. The metastable transformation is reversed upon illumination of above-band-gap light, at which point the nanocrys...

This paper reports the detailed preparation process of Eu2+ activated long lasting Sr4Al14O25 nano sized phosphor by precipitation method. Scanning electron microscopy (SEM), simultaneous DSC–TG, X-ray diffraction (XRD), photo luminescent spectroscope (PLS) and thermal luminescent (TL) spectroscope were employed to characterize the phosphor. SrAl2O4:EuDy and Sr4Al14O25:EuDy phosphors in nano sc...

Luminescent waveguides (LWs) occur in a wide range of applications, from solar concentrators to doped fiber amplifiers. Here we report a comprehensive analysis of escape-cone losses in LWs, which are losses associated with internal rays making an angle less than the critical angle with a waveguide surface. For applications such as luminescent solar concentrators, escape-cone losses often domina...