Rare earth doped glass-ceramics transparent in the infrared region up to 16 μm have been prepared and studied. The enhancement of the emission of Er 3+ ions at 1.54 μm with increasing crystallinity was demonstrated in a seleniumbased glass-ceramic having a composition of 80GeSe2-20Ga2Se3+1000 ppm Er. The optical transmission, microstructure and luminescence properties of a base glass and glass-...

The luminescence thermochromism properties of two entangled copper(I)-iodide coordination polymers formulated [Cu4I4(dmimpr)2]n (1) and [Cu6I6(dimb)3]n (2) (dmimpr = 1,3-di(2-methyl-imidazol-1-yl)propane, dimb = 1,4-di(imidazol-1-yl)butane) are reported. Upon cooling by liquid nitrogen, their solid-state luminescences at room temperature are drastically changed with the large red-shifts of 41 a...

Two isostructural transition-metal (TM) triphosphonates decorated with neutral rigid N-containing ligands 1,3,5-tris(1-imidazolyl)benzene (tib), [Zn3(L1)(tib)]·8H2O (1) and [Co3(L1)(tib)]·9H2O (2) (H6L1 = N(CH2PO3H2)3), nitrilotris(methylenephosphonic acid), have been solvothermally prepared and structurally characterized by infrared spectroscopy, elemental analysis, thermogravimetric analysis ...

The effect of carbon monoxide on the luminescence properties of Helix pomatia alpha-hemocyanin and Panulirus interruptus hemocyanin has been studied. These proteins, when saturated with carbon monoxide, show, besides the intrinsic fluorescence arising from the aromatic amino acid residues, emission in the visible region with a maximum between 540 and 560 nm. Results of carbon monoxide titration...

Photoluminescence has been exploited to characterize materials non-destructively since the early development of scientific studies on archaeological and cultural heritage materials [1]. First used as tool for qualitative visual examination of objects, luminescence spectroscopy, carried out at macroand micro-scale, allowed characterizing luminescence properties of cultural heritage and artists’ ...

For more than 70 years, researchers in several areas of science have been intrigued by the physical and chemical properties of the lowest excited states of molecular oxygen. With two singlet states lying close above its triplet ground state, the O2 molecule possesses a very unique configuration, which gives rise to a very rich and easily accessible chemistry, and also to a number of important p...

A new zinc phosphite exhibited remarkable structural transformations upon heat stimulation to convert into a dehydrated form (NCU-2a) and a new structure, NCU-2b. The gas adsorption properties of the materials as well as the luminescence properties of LED devices fabricated using these materials were also investigated.

viable cell concentration and luminescence activity of p. stutzeri p16 luxab4 was measured byplate counting and luminometery in sterile and non-sterile soil adjusted to matric potential of -1500, -750 and-30 kpa. results showed that matric potential had a significant effect on survival and activity of p. stutzerip16 luxab4 in soil. p. stutzeri p16 luxab4 could survive better in hutner’s minimal...

Local variations in the optical properties of thick In0.13Ga0.87As films grown on GaAs~001! substrates misoriented toward $111% planes have been studied with polarized and spectrally-resolved cathodoluminescence ~CL! imaging. The degree of anisotropic relaxation and density of dark line defects ~DLDs! in CL was found to depend on the choice of the substrate miscut orientation. An enhanced aniso...

This study has investigated the effect of dopant concentration on the luminescent emission of Er in ZrO2 nanocrystals. The structure and morphology of the resulting nanocrystals were characterized by X-ray diffraction and field emission scanning electron microscope. The room-temperature optical properties of synthesized nanocrystals were studied by photoluminescence spectroscopy. The dependence...