The thermoluminescence (TL) and EPR spectra of nanostructured compacts monoclinic ZrO 2 irradiated by three types irradiation have been studied: impulse flow 130 keV electrons, beam 10 MeV as well a 220 Xe ion beam. Irradiation samples with electrons ions leads to the formation F + centers in them. Thermal destruction these is observed temperature range 375–550 K for electron-irradiated 500– 70...