Liquid-liquid extraction or solid-phase extraction followed by gas chromatography (GC) or high-performance liquid chromatography are traditional herbicide residue determination methods for environmental samples. Solid-phase microextraction (SPME) is a solventless, fast, and sensitive alternative herbicide residue extraction method that can be applied to numerous environmental matrices. The obje...

Abstract Organotin compounds are widely employed as pesticides and fungicides in agriculture stabilizers for the industrial manufacture of polyvinyl chloride other polymers. Accordingly, these endocrine disruptors can be found a variety foods beverages. In present study, we describe optimization hollow-fiber liquid-phase micro-extraction approach simultaneous derivatization, extraction, pre-con...

Liquid-liquid extraction is a widespread separation technique with applications in the analytical and the organic chemistry laboratory (13). A problem often tackled in textbooks is the efficiency of several extractions using small portions of solvent in relation to a single extraction with a volume of solvent equal to the sum of the small portions. I t is shown in most textbooks, with the aid o...

The droplet size distribution in the column is usually represented as the average volume to surface area, known as the Sauter mean drop diameter. It is a key variable in the extraction column design. A study of the drop size distribution and Sauter-mean drop diameter for a liquid-liquid extraction column has been presented for a range of operating conditions and three different liquid-liquid sy...

Direct analysis by mass spectrometry (imaging) has become increasingly deployed in preclinical and clinical research due to its rapid and accurate readouts. However, when it comes to biomarker discovery or histopathological diagnostics, more sensitive and in-depth profiling from localized areas is required. We developed a comprehensive, fully automated online platform for high-resolution liquid...

The extraction behavior of several divalent metal cations (M(2+)) in ionic liquid chelate extraction systems was investigated using several 1-alkyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ionic liquids ([Rmim][Tf(2)N]) as extraction solvent and thenoyltrifluoroacetone (Htta) as extractant. The behavior was compared with that using less hydrophobic 1-alkyl-3-methylimidazolium hexa...

Liquid marbles can be used as micro-bioreactors, thanks to their unique properties. On the one hand, the highly porous, non-adhesive, and hydrophobic shell of liquid marbles efficiently inhibits any direct contact between the liquid core of the marble and the surface that supports it, while allowing oxygen and carbon dioxide to pass through. On the other hand, the finite volume of liquid in liq...

objective(s):the present study reports the development and validation of a sensitive and rapid extraction method beside high performance liquid chromatographic method for the determination of crocetin in human serum. materials and methods:the hplc method was carried out by using a c18 reversed-phase column and a mobile phase composed of methanol/water/acetic acid (85:14.5:0.5 v/v/v) at the flow...