Introduction: There are different methods for removal of cadmium from aqueous solutions. Adsorption based methods are among the bests. One of the most important aspects for adsorption techniques is the availability of an accessible and economical adsorbent. This study aims to investigate cadmium removal from aqueous solutions by walnuts shell waste. Materials and Methods: Walnut Shell (WS) was...

The kinetics and isotherm studies of the immobilized lipase and the mechanism of immobilization on chitosan beads and activated chitosan beads with glutaraldehyde were investigated. The effect of glutaraldehyde on porosity of chitosan was evaluated by FESEM analysis. It was observed that the porosity of the carrier which has activated by glutaraldehyde was substantially increased. The validity ...

A semimechanistic multi-reaction kinetic model was developed to describe the enzymatic hydrolysis of a lignocellulosic biomass, creeping wild ryegrass (CWR; Leymus triticoides). This model incorporated one homogeneous reaction of cellobiose-to-glucose and two heterogeneous reactions of cellulose-to-cellobiose and cellulose-to-glucose. Adsorption of cellulase onto pretreated CWR during enzymatic...

Control of nonspecific protein adsorption is very important for the design of biocompatible and biomimetic materials as well as drug carriers. Grafted polymer layers can be used to prevent protein adsorption. We have studied the molecular factors that determine the equilibrium and kinetic control of protein adsorption by grafted polymer layers. We find that polymers that are not attracted to th...

The statistical rate theory (SRT) fundamental kinetic equation for the Langmuir model of adsorption reveals some features which are difficult to understand. These are the infinitely high adsorption rate for zero coverage limit, infinitely high desorption rate at full saturation of the surface and dependence of the desorption rate on the adsorbate pressure. These features do not allow for a corr...

The adsorption characteristics of methylene blue (MB) onto needles of Pinus sylvestris L., an unconventional bio-adsorbent, were investigated. Maximum removal of MB was found to occur at initial pH 5. Adsorption capacity increased from 84.46 to 99.73 mg/g with an increase in temperature from 20 to 45°C at 200 mg/L of initial MB concentration. Adsorption isotherms were modeled with the Langmuir,...

This research presents adsorption potential of surfactant (sodium dodecyl sulphate; SDS) coated magnetite nanoparticles as suitable and efficient adsorbent for the removal of Basic Blue 41 (BB 41), as a cationic dye from textile’s company wastewater. The effects of various experimental parameters (e.g. initial pH of the solution, SDS amount, and ionic strength) on the adsorption efficiency of B...

In this study, Saccharum bengalense(SB) was used as biosorbent for the removal of Mn (II) ions from aqueous solution. The influence of biosorbent dose, time, pH and temperature was investigated in the biosorption process. Studies showed that by increasing pH of the solution, metal removing efficiency of Saccharum bengalensefrom the aqueous environment was enhanced but to a specific extent, ...

The mechanism, isotherms and kinetics of removal of two endocrine disrupting chemicals, 17β-estradiol (E2) and 17αethinyloestradiol (EE2) by activated carbon adsorption were investigated in an agitated non-flow batch adsorption studies. Mathematical models were used to describe the adsorption phenomenon with the kinetic and thermodynamic parameters evaluated using the adsorption equilibrium dat...