We report kinetic molecular sieving of hydrogen and deuterium in zeolite rho at low temperatures, using atomistic molecular dynamics simulations incorporating quantum effects via the Feynman-Hibbs approach. We find that diffusivities of confined molecules decrease when quantum effects are considered, in contrast with bulk fluids which show an increase. Indeed, at low temperatures, a reverse kin...

The separation factor, aM-0= ( 1 8 0 / 1 6 0 ) magnetite/' ( 1 8 0 / 1 6 0 ) atmospheric oxygen, between the magnetite crust of iron meteorites and atmospheric oxygen has been determined to be 0.9946 ± 0.0005. It is concluded that this fractionation of the oxygen isotopes is the consequence of an equilibrium isotope effect at high temperatures. It can be assumed that this is also valid for cosm...

This paper presents results of statistical calculations of single-particle characteristics of nuclei, excitation energies and shape transition in the Sn isotope with neutron number 50, which is the extremely neutron deficient isotope. It is a very rare and unstable isotope which does not occur in nature, but only on the surface of exploding stars for less than a second. The spherical nucleus at...

An efficient membrane for helium separation from natural gas is quite crucial for cryogenic industries. However, most experimentally available membranes fail in separating helium from small molecules in natural gas, such as H2, as well as in 3He/4He isotopes separation. Using first-principles calculations, we theoretically demonstrated that the already-synthesized graphitic carbon nitride (g-C3...

Rotating plasmas have the potential to offer unique capabilities for isotope and mass separation. Among the various electric and magnetic field configurations offering mass separation capabilities, rotating plasmas produced through static or oscillating fields are shown to be a leading candidate for tackling the unsolved problem of large-scale plasma separation. The successful development and d...

Isotope effect may cause partial chromatographic separation of labeled (heavy) and unlabeled (light) isotopologue pairs. Together with a simultaneous matrix effect, this could lead to unacceptable accuracy in quantitative liquid chromatography-mass spectrometry assays, especially when electrospray ionization is used. Four biologically relevant reactive aldehydes (acrolein, malondialdehyde, 4-hy...