Using the strong electromagnetic fields in peripheral heavy ion collisions gives rise to a number of interesting possibilities of applications in both photon-photon and photon-hadron physics. We look at the theoretical foundations of the equivalent photon approximation and the specific problems in the heavy ion case. The interesting physics processes that can be studied in this way are outlined...

As part of an ongoing study to identify selenium compounds with cancer chemopreventive activity, extracts of selenium-enriched samples were analyzed by HPLC-inductively coupled plasma (ICP)-MS. Ion-exchange, ion pair and derivatization methods for reversed-phase HPLC were considered and advantages and disadvantages for each compared. Anion exchange allows separation of selenite and selenate, bu...

The extraction and separation of copper(II), zinc(II), cobalt(II), and cadmium(II) were investigated. Both copper(II) and zinc(II) formed ammine-complexes, while cadmium(II) and cobalt(II) formed hydroxide precipitates in an ammonia medium. By the addition of sodium dodecylsulfate (SDS), a copper(II) complex formed an ion-pair (copper-ammine-DS), which was extracted into the SDS phase. However,...

We calculate the spatial correlation of electrons and positrons emitted by internal pair conversion of Coulomb excited nuclei in heavy ion collisions. The alignment or polarization of the nucleus results in an anisotropic emission of the electron-positron pairs which is closely related to the anisotropic emission of γ-rays. However, the angular correlation in the case of internal pair conversio...

We calculate the spatial correlation of electrons and positrons emitted by internal pair conversion of Coulomb excited nuclei in heavy ion collisions. The alignment or polarization of the nucleus results in an anisotropic emission of the electron-positron pairs which is closely related to the anisotropic emission of γ-rays. However, the angular correlation in the case of internal pair conversio...

To explore how the ion-pair in a single salt molecule evolves with the addition of water, infrared (IR) spectra of complexes composed of NaCl and multiple water molecules have been recorded for the first time. The NaCl(H2O)n complexes were formed and probed in liquid helium nanodroplets, and IR spectra were recorded for n = 1 → 4. The spectra for n = 1, 2, and 3 are consistent with formation of...

Catalytic use of peroxomolybdate for asymmetric transformations has attracted increasing attention due to its catalytic properties and application in catalysis. Herein, we report chiral bisguanidinium dinuclear oxodiperoxomolybdosulfate [BG]2+[(μ-SO4)Mo2O2(μ-O2)2(O2)2]2- ion pair, as a catalyst for enantioselective sulfoxidation using aqueous H2O2 as the terminal oxidant. The ion pair catalyst ...

Complex formation and intermolecular excited-state proton transfer (ESPT) between a dihydroxy-1,8-naphthalimide photoacid and organic bases are investigated in polar aprotic solvents. First, quantum chemical calculations are used to explore the acid-base and spectroscopic properties and to identify energetically favorable complexes. The two hydroxyl groups of the photoacid enable stepwise forma...

Abstract Astrophysical jets are ubiquitous in the universe and often associated with compact objects, their interactions ambient medium not only dissipate own energy but also provide ideal circumstances for particle acceleration. By means of theoretical analysis particle-in-cell simulations, here we study ion acoustic shock wave (IASW) formation consequent acceleration when electron–positron ( ...

Five solutions of sodium chloride in mixtures of water and dimethyl sulphoxide ͑DMSO͒ have been simulated using the conventional molecular dynamics technique. The potentials of mean force ͑PMFs͒ of the sodium chloride ion pair in the presence of the five water–DMSO mixtures with DMSO mole fractions (x DMSO) of 0.10, 0.21, 0.35, 0.48 and 0.91 have been computed. The derived PMFs have been confirmed ...