The storage and loss moduli for jammed soft particles are studied computationally a variety of interparticle potentials volume fractions. qualitative behavior the modulus is independent nature potential. frequency dependence computed in simulations described by universal logistic formula exhibiting two plateaus at low high frequencies. While high-frequency G∞ follows prediction Zwanzig–Mountain...

A method is presented to control the in-plane ordering, size, and interparticle distance of nanoparticles fabricated by evaporation through a mask of colloidal particles. The use of optical tweezers combined with critical point drying gives single-particle position control over the colloidal particles in the mask. This extends the geometry of the colloidal masks from (self-organized) hexagonal ...

Maghemite (γ-Fe2O3) nanoparticles (NPs) can be successfully dispersed in a protic ionic liquid, ethylammonium nitrate (EAN), by transfer from aqueous dispersions into EAN. As the aqueous systems are well controlled, several parameters can be tuned. Their crucial role towards the interparticle potential and the structure of the dispersions is evidenced: (i) the size of the NPs tunes the interpar...

The size of gold nanoparticle aggregates was controlled by manipulating the interparticle interaction. To manipulate the interparticle interaction of gold nanoparticles prepared by citrate reduction, we applied the substitutive adsorption of benzyl mercaptan on the particle surface in the absence of the cross-linking effect. Various experimental techniques such as UV-vis absorption spectroscopy...

Self-assembly of nanoparticles (NPs) into tailored structures is a promising strategy for the production and design of materials with new functions. In this work, 2D arrays of iron oxide NPs with interparticle distances tuned by grafting fatty acids and dendritic molecules at the NPs surface have been obtained over large areas with high density using the Langmuir-Blodgett technique. The anchori...

The most important microstructural processes involved in shock consolidation are identified and illustrated for a nickel-based superalloy and silicon carbide. Interparticle melting, vorticity, voids, and particle fracture are observed. Various energy dissipation processes are identified and analyzed: plastic deformation, interparticle friction, microkmetic energy, defect generation. An analytic...

We study ultrafast excitonic population inversion resulting from the interaction of a semiconductor quantum dot (SQD) with localized surface plasmons. The plasmonic enhanced fields are generated when a metallic nanoparticle (MNP) is subject to a nonlinear chirped few-cycle pulse train. By numerically solving the time-dependent Bloch equations beyond the rotating-wave approximation, we show that...

TiC-supported sizeand shape-selected Au nanoparticles with well defined interparticle distances were synthesized by diblock copolymer encapsulation. Atomic force microscopy (AFM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and temperature programmed desorption (TPD) have been used to investigate the correlation between the nanocatalyst morphological/ electron...

A nanoparticle-based strategy has been demonstrated using structurally-tailored tert-butylcalixarenes immobilized on gold nanoparticles to tune the guest access to the calixarene cone cavity for cationic recognition. This strategy exploits the interparticle charge-induced aggregation upon selective capture of metal cations into the nanoparticle-immobilized tert-butylcalixarenes, which produces ...

Near-field dipolar plasmon interactions of multiple infrared antenna structures in the strong coupling limit are studied using scattering-type scanning near-field optical microscope (s-SNOM) and theoretical finite-difference time-domain (FDTD) calculations. We monitor in real-space the evolution of plasmon dipolar mode of a stationary antenna structure as multiple resonantly matched dipolar pla...