Semiconducting group 14 clathrates are inorganic host-guest materials with a close structural relationship to gas hydrates. Here we utilize this inherent structural relationship to derive a new class of porous semiconductor materials: noble gas filled group 14 clathrates (Ngx[M136], Ng = Ar, Kr, Xe and M = Si, Ge, Sn). We have carried out highlevel quantum chemical studies using periodic Local-...

We study the phase diagram and orientational ordering of guest liquid crystalline (LC) rods immersed in a quenched host made of a liquid crystalline polymer (LCP) matrix with mobile side chains. The LCP matrix lies below the glass transition of the polymer backbone. The side chains are mobile and can align to the guest rod molecules in a plane normal to the local LCP chain contour. A field theo...

The formation of host-guest cyclic architectures, built up through the self-condensation process of [Mo(2)O(2)S(2)](2+) oxothiocations around linear dicarboxylate ions such as adipate (Adip(2-)), suberate (Sub(2-)) and azelaate (Azel(2-)) anions is reported. The complexes [Mo(12)Adip](2-), [Mo(12)Sub](2-) and [Mo(14)Azel](2-) have been characterized in the solid state by X-ray diffraction and i...

The complexation of (3aR,7aR)-N-(3,5-bis(trifluoromethyl)phenyl)octahydro-2H-benzo[d]imidazol-2-imine (BTI), as a guest, to ethane-bridged bis(zinc octaethylporphyrin), bis(ZnOEP), host, has been studied by means ultraviolet-visible (UV-Vis) and circular dichroism (CD) absorption spectroscopies, single crystal X-ray diffraction, computational simulation. formation 1:2 host-guest complex was est...

The synthesis of 5,10,15,20-tetrakis((5,10-bis((2-hexyldecyl)oxy)dithieno[3,2-c:3?,2?-h][1,5]naphthyridin-2-yl)ethynyl)porphyrin zinc(II) (Por4NT), a near-infrared (NIR) emitting compound, comprising zinc porphyrin core linked with triple bonds through its meso positions to four 5,10-bis((2-hexyldecyl)oxy)dithieno[3,2-c:3?,2?-h][1,5]naphthyridine (NT) arms is reported. Por4NT featured high solu...

The fibrous architecture of the extracellular matrix (ECM) is recognized as an integral regulator cell function. However, there unmet need to develop mechanically robust biomaterials mimicking nanofibrous tissue topography that are also injectable enable minimally invasive delivery. In this study, we have developed a hydrogel composed supramolecularly assembled hyaluronic acid (HA) nanofibers e...

A set of four hybrid host-guest complexes based on the inorganic crown ether analogue [H12W36O120]12- ({W36}) have been isolated and characterised. The cluster anion features a central rigid binding site made up of six terminal oxygen ligands and this motif allows the selective binding of a range of alkali and alkali-earth-metal cations. Here, the binding site was utilised to functionalise the ...

The host-guest interactions play a very important role in chemical and biological processes. It is therefore important to be able to characterize these complexes. Electrospray mass spectrometry can be used to characterize the complex formation. It provides information on the mass and the charge of these ionic complexes. In this article, we show that the use of ab initio and semiempirical calcul...

The malicious alteration of machine time is a big challenge in computer forensics. Detecting such changes and reconstructing the actual timeline of events is of paramount importance. However, this can be difficult since the attacker has many opportunities and means to hide such changes. In particular, cloud computing, host and guest machine time can be manipulated in various ways by an attacker...

CO2 capture on solid materials possesses significant advantages on the operation cost, process for large-scale CO2 capture and storage (CCS) that stimulates great interest in exploring high-performance solid CO2 adsorbents. A ship-in-a-bottle strategy was successfully developed to prepare the [APMIM]Br@NaY host-guest system in which an amine-functionalized ionic liquid (IL), 1-aminopropyl-3-met...