In this study, we perform steady-state and time-resolved X-ray absorption spectroscopy (XAS) on the iron K-edge of [Fe(tren(py)3)](PF6)2 dissolved in acetonitrile solution. Static XAS measurements on the low-spin parent compound and its high-spin analogue, [Fe(tren(6-Me-py)3)](PF6)2, reveal distinct spectroscopic signatures for the two spin states in the X-ray absorption near-edge structure (XA...

in this paper, we study the electronic properties of a concentric triple quantum ring using exact diagonalization technique. the energy spectra and magnetization for a single electron and two electrons, in the presence of an applied magnetic field, are calculated and discussed. it is shown that, for two-interacting electrons, the period of aharonov-bohm oscillations decreases to the half of tha...

We study the magnetic susceptibility of mixed-valent La2−xSrxCoO4 single crystals in the doping range of 0.5 x 0.8 for temperatures up to 1000 K. The magnetism below room temperature is described by paramagnetic Co2+ in the high-spin state and by Co3+ in the nonmagnetic low-spin state. At high temperatures, an increase in susceptibility is seen, which we attribute to a temperature-induced spin-...

Received 25 August 2021DOI:https://doi.org/10.1103/PhysRevC.105.029903©2022 American Physical Society

The doping process of helium nanodroplets with alkali atoms has been modeled in order to study deviations from the Poissonian statistics of measured pick-up statistics which are important for assigning cluster or complex sizes in many experimental studies. Several, formally unexplained findings are reproduced and their origin has been analyzed: derivations from the expected functional form of t...

Helium nanodroplet isolation has been applied to agglomerate alkali clusters at temperatures of 380 mK. The very weak binding to the surface of the droplets allows a selection of only weakly bound, high-spin states. Here we show that larger clusters of alkali atoms in high-spin states can be formed. The lack of strong bonds from pairing electrons makes these systems nonmetallic, van der Waals-l...