The homogeneity range and crystal structure of the Mg-rich ternary solid solution has been determined using SEM, EPMA/WDS, TEM and X-ray diffraction. This compound has the Ca3MgxZn15 x (4.6 x 12) formula at 335 C. The refinement of the XRD patterns was carried out by Rietveld analysis, XRD data has shown that this solid solution crystallizes in hexagonal structure having P63/mmc (194) space gro...