نتایج جستجو برای: heterogenized catalyst

تعداد نتایج: 44082  

1996
Z. Sun T. Örs B. G. Evans

This paper presents the performance studies of ATM via satellite based on experiments implemented by the RACE II CATALYST project R2074. The purpose of the project was to develop an ATM satellite link for the future B-ISDN services, particularly for the interconnections of the ATM testbeds which are in the form of broadband islands. Then initial ATM based B-ISDN can be introduced by interconnec...

Journal: :journal of nanostructures 2015
h. khojasteh v. mirkhani m. moghadam s. tangestaninejad i. mohammadpoor-baltork

palladium is the best metal catalyst for suzuki cross coupling reaction for synthesize of unsymmetrical biaryl compounds. but its high cost limits its application in wide scale. using of nanoscale particles as active catalytic cites is a good approach for reducing needed noble metal. by loading precious nanoparticles on magnetic nanocores as a support, recycling and reusing of catalyst will be ...

2014
Ryan O'Hayre Kevin N. Wood Svitlana Pylypenko Arrelaine A. Dameron Tim S. Olson Guido Bender Huyen N. Dinh Thomas Gennett Ryan M. Richards

Effect of nitrogen post-doping on a commercial platinum–ruthenium/carbon anode catalyst Report Title This work investigates the effects of after-the-fact chemical modification of a state-of-the-art commercial carbonsupported PtRu catalyst for direct methanol fuel cells (DMFCs). A commercial PtRu/C (JM HiSPEC-10000) catalyst is post-doped with nitrogen by ion-implantation, where “post-doped” den...

Journal: :ChemSusChem 2015
Matthew B Chambers Xia Wang Noémie Elgrishi Christopher H Hendon Aron Walsh Jonathan Bonnefoy Jérôme Canivet Elsje Alessandra Quadrelli David Farrusseng Caroline Mellot-Draznieks Marc Fontecave

The first photosensitization of a rhodium-based catalytic system for CO2 reduction is reported, with formate as the sole carbon-containing product. Formate has wide industrial applications and is seen as valuable within fuel cell technologies as well as an interesting H2 -storage compound. Heterogenization of molecular rhodium catalysts is accomplished via the synthesis, post-synthetic linker e...

Journal: :Journal of the American Chemical Society 2004
Bradley A Steinhoff Ilia A Guzei Shannon S Stahl

The Pd(OAc)(2)/pyridine catalyst system is one of the most convenient and versatile catalyst systems for selective aerobic oxidation of organic substrates. This report describes the catalytic mechanism of Pd(OAc)(2)/pyridine-mediated oxidation of benzyl alcohol, which has been studied by gas-uptake kinetic methods and (1)H NMR spectroscopy. The data reveal that turnover-limiting substrate oxida...

2015
Tomoyo Goto Toshio Itoh Takafumi Akamatsu Woosuck Shin

The CO sensing properties of a micro thermoelectric gas sensor (micro-TGS) with a double AuPtPd/SnO₂ and Pt/α-Al₂O₃ catalyst were investigated. While several nanometer sized Pt and Pd particles were uniformly dispersed on SnO₂, the Au particles were aggregated as particles measuring >10 nm in diameter. In situ diffuse reflectance Fourier transform Infrared spectroscopy (DRIFT) analysis of the c...

2017
Wenda Zhu Jacek A. Koziel Devin L. Maurer

Concentrated livestock feeding operations have become a source of odorous gas emissions that impact air quality. Comprehensive and practical technologies are needed for a sustainable mitigation of the emissions. In this study, we advance the concept of using a catalyst for barn walls and ceilings for odor mitigation. Two catalysts, a new TiO2-based catalyst, PureTi Clean, and a conventional Evo...

2014
Ga Vin Kim WoonYong Choi DoHyung Kang ShinYoung Lee HyeonYong Lee

The aim of this study was to increase the yield of biodiesel produced by Scenedesmus sp. through in situ transesterification by optimizing various process parameters. Based on the orthogonal matrix analysis for the acidic catalyst, the effects of the factors decreased in the order of reaction temperature (47.5%) > solvent quantity (26.7%) > reaction time (17.5%) > catalyst amount (8.3%). Based ...

2006
Mitsuharu Chisaka

In polymer electrolyte membrane fuel cells (PEMFCs), because the reaction rate in the cathode is slower than that in the anode, the cathode catalyst layers require more catalyst loading than the anodes [1]. Much research has been focused on improving the catalytic activity in cathodes and simultaneously reducing the amount of Pt supported by carbon black, which is the most commonly used cathode...

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