Aiming at designing ionic liquids for the purification of natural gas, the solubility of methane in ionic liquids is investigated here through the measurement of the solubilities of methane in four ionic liquids (ILs), in a wide range of molar fractions, temperature and pressures. With the exception of the phosphonium-based IL, which behaves as an almost ideal solution, the other ionic liquids ...

Choline saccharinate and choline acesulfamate are two examples of hydrophilic ionic liquids, which can be prepared from easily available starting materials (choline chloride and a non-nutritive sweetener). The (eco)toxicity of these ionic liquids in aqueous solution is very low in comparison to other types of ionic liquids. A general method for the synthesis and purification of hydrophilic ioni...

Quasielectrons and quasiholes in the fractional quantum Hall liquids obey fractional (including nontrivial mutual) exclusion statistics. Their statistics matrix can be determined from several possible state-counting scheme, involving different assumptions on statistical correlations. Thermal activation of quasiparticle pairs and thermodynamic properties of the fractional quantum Hall liquids ne...

The design and fabrication of textured surfaces has received much attention during the past decade. In case of a hydrophobic texture a modified surface profile can lead to a very large contact angle, which induces exceptional wetting properties. A remarkable mobility of liquids on such SH surfaces is observed in the Cassie state, where the textures are filled with gas, which renders them “self-...

Overall liquid side volumetric mass transfer coefficient kLa was determined experimentally for cocurrent Taylor flow moving upwards in a glass tube of an internal diameter of 3mm. Experiments were performed for physical absorption of oxygen in 20% aqueous solution of ethanol. Shadowgraph technique was deployed for precise measurements of bubble lengths and velocities. Experimental values of vol...

It is also common for flowmeters to be installed downstream of a two or three phase separator. If the well conditions change or the separator has been incorrectly sized, then it is possible that the oil liquid outlet may have some gas carry under. The effects of gas entrainment on the output of ultrasonic and Coriolis meters has been reported previously [1] [2]. It is already known that gas ent...

bifunctional acidic ionic liquids, having both h-imidazolium and -so3h groups as cation moieties (h-bfails) and cf3so3- as anion, were synthesized in high yields. these h-bfails showed significant hydrophilic properties, lower acidity and higher thermal stability relative to common ionic liquids, due to their unique structures. the (propyl or butyl-3-sulfonic) imidazolium trifluoromethane sulfo...

The thermal stability of a series of dialkylimidazolium carboxylate ionic liquids has been investigated using a broad range of experimental and computational techniques. Ionic liquids incorporating fluoroalkyl carboxylate anions were found to have profoundly differing thermal stabilities and decomposition mechanisms compared with their non-fluorinated analogues. 1-Ethyl-3-methylimidazolium acet...

In this contribution a micro liquid dosing system is presented, which allows bi-directional manipulation of fluids (i.e. pushing out and pulling in of liquids) by the electrochemical generation and removal of gas bubbles. Bi-directionality is obtained by reversal of the actuation current thereby causing the earlier produced gasses to react back to water. This reduction of gas volume actively pu...

Introduction. Laboratory data on the evaporation kinetics and isotope fractionation of evaporation residues of silicate liquids exposed to vacuum or lowpressure gas of solar or dust-enriched compositions provide constraints on processes that affected the evolution of primitive inclusions in meteorites. In earlier work we focused on evaporations of Type B CAI-like liquids [1,4]. Here we will ree...