The local solid flow structure of gas-solid bubbling fluidized bed was investigated to identify and characterize the particle clusters. Extensive mathematical calculations were carried out using the energy-minimization multi-scale (EMMS) approach for evaluating cluster properties including the velocity, the size and the void fraction of clusters in the dense phase of the bed. The results showed...

in this paper, the effect of surface area of reaction layers in gas diffusion electrodes on oxygen reduction reaction was investigated. for this purpose, various amounts (0.1, 0.2, 0.3, 0.4, 0.5, 1, 1.5 and zero %wt of total loading of reaction layer) of single walled carbon nanotube (swcnt) were inserted in the reaction layer. the performance of gas diffusion electrodes for oxygen reduction re...

INTRODUCTION To account for meso-scale phenomena in coarse grid simulations, Reynolds stress terms appearing in the filtered gas-solid flow equations have to be modeled. Filtered models for the gas-solid momentum transfer are focused on and possible approaches are discussed. Three-dimensional steady-state simulations of developing flow in the bottom section of a riser in which the solid phase i...

The soot combustion mechanism over potassium-supported oxides (MgO, CeO2 and ZrO2) was studied to clarify the active sites and discover unified reaction intermediates in this typical gas-solid-solid catalytic reaction. The catalytically active sites were identified as free K(+) rather than K2CO3, which can activate gaseous oxygen. The active oxygen spills over to soot and forms a common interme...

A reacting packed-bed undergoing a high-temperature thermochemical solid-gas transformation is considered. The steamand dry-gasification of carbonaceous materials to syngas is selected as the model reaction. The exact 3D digital geometrical representation of the packed-bed is obtained by computer tomography and used in direct pore-level simulations to characterize its morphological and radiativ...

In the current work the kinetics of dehydration of ziprasidone hydrochloride monohydrate was studied by nonisothermal thermogravimetry. Ziprasidone hydrochloride monohydrate was heated from 30 to 150° with a heating rate of 5° per min under nitrogen gas atmosphere and weight loss data were collected. Powder X-ray difraction was used to characterize the solid before and after dehydration. The we...

Because of its high electrical conductivity and good diffusion barrier properties ruthenium dioxide (RuO2) is a good electrode material for use with ferroelectric lead zirconate–titanate (PZT) solid solutions. Under certain conditions, RuO2 can react with PZT to form lead ruthenate (Pb2Ru2O6⋅5) during processing at elevated temperatures resulting in lead depletion from PZT. The standard Gibbs e...