Neutron diffraction runs and gas-consumption experiments based on pressure-volume-temperature measurements are conducted to study the kinetics of methane hydrate formation from hydrogenated and deuterated ice powder samples in the temperature range of 245-270 K up to high degrees of transformation. An improved theory of the hydrate growth in a polydisperse ensemble of randomly packed ice sphere...

In this study, the kinetics of gas hydrate formation in the presence of tetra-n-butyl ammonium fluoride (TBAF) and cetyl trimethyl ammonium bromide surface active ingredient (CTAB) with zinc nano oxide (ZnO) are investigated and the most important kinetic parameters of hydrate formation such as their induction time and storage capacity were measured. The kinetic experiments were carried out in ...

Gas Hydrates are widely distributed in the near surface at high latitudes and many ocean bottoms. Our laboratory measurements help calibrate the seismic and well log data that are used to ascertain the in situ distribution of hydrates. Ultrasonic velocities are measured in unconsolidated sand specimen under thermobaric conditions comparable to those found in shallow oceanic or permafrost region...

During Ocean Drilling Program (ODP) Leg 204, we will drill a transect of sites through the gas hydrate stability zone on the southern part of Hydrate Ridge on the Cascadia accretionary margin offshore Oregon. Massive hydrates are present at the seafloor there, and high-resolution threedimensional seismic data indicate a complicated subsurface plumbing system. The transect will cover two distinc...

Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclose...

In this study we evaluate the response of oceanic subsurface systems to thermal stresses caused by the flow of warm fluids through non-insulated well systems crossing hydrate-bearing sediments. Heat transport from warm fluids, originating from deeper reservoirs under production, into the geologic media can cause dissociation of the gas hydrates. The objective of this study is to determine wheth...

The recovery of natural gas from CH4-hydrate deposits in sub-marine and sub-permafrost environments through injection of CO2 is considered a suitable strategy towards emission-neutral energy production. This study shows that the injection of hot, supercritical CO2 is particularly promising. The addition of heat triggers the dissociation of CH4-hydrate while the CO2, once thermally equilibrated,...

Industrial biotechnology has not developed as fast as expected due to some challenges including the emergences of alternative energy sources, especially shale gas, natural gas hydrate (or gas hydrate) and sand oil et al. The weaknesses of microbial or enzymatic processes compared with the chemical processing also make industrial biotech products less competitive with the chemical ones. However,...

The recovery of CH4 gas from natural hydrate formations by injection of industrially emitted CO2 is considered to be a promising solution to simultaneously access an unconventional fossil fuel reserve and counteract atmospheric CO2 increase. CO2 obtained from industrial processes may contain traces of impurities such as SO2 or NOx and natural gas hydrates may contain higher hydrocarbons such as...

Concerns about the potential effects of rising carbon dioxide levels in the atmosphere have stimulated interest in a number of carbon dioxide sequestration studies. One suggestion is the sequestration of carbon dioxide as clathrate hydrates by injection of carbon dioxide into methane hydrate. Energy-supply research estimates indicate that natural gas hydrates in arctic and sub-seafloor formatio...