A Microsoft Excel spreadsheet has been programmed that allows users to calculate with ease the molar proportions of garnet end-members from chemical analyses. Recent advances in the understanding of the crystal chemistry of natural garnets, especially of the Ti-bearing garnets, are used to evaluate 29 end-members (15 species and 14 hypothetical end-members) for each analysis. The amounts of Fe ...

In situ analysis reveals that eclogite-facies garnets are zoned in dO with lower values in the core and rims that are *1.5 to 2.5 % higher. This pattern is present in 9 out of 12 garnets analyzed by SIMS from four orogenic eclogite terranes, and correlates with an increase in the mole fraction of pyrope and Mg/Fe ratio from core to rim, indicating prograde garnet growth. At the maximum temperat...

Fast ion conducting garnet materials have been identified as promising electrolytes for all solid-state batteries. However, reliable synthetic routes to materials with fully elucidated cation site occupancies where an enhancement in lithium conductivity is observed remains a challenge. Ca-Incorporation is developed here as a promising approach to enhance the ionic conductivity of garnet-type Li...

Lithium-stuffed garnets attract huge attention due to their outstanding potential as solid-state electrolytes for lithium batteries. However, there exists a persistent challenge in the reliable synthesis of these complex functional oxides together with a lack of complete understanding of the lithium-ion diffusion mechanisms in these important materials. Addressing these issues is critical to re...

New geochemical data for Pleistocene magmatic rocks from the Surigao peninsula, eastern Mindanao, the Philippines, demonstrate typical adakitic traits, including elevation of Sr /Y and depletion of the heavy rare earth elements. Sr / Sr and Nd / Nd ratios of the adakites do not support melting of the subducted Philippine Sea Plate but resemble Pliocene arc lavas generated in the same subduction...

Thermal conductivity at room temperature and pressure (k0), and heat capacity and total entropy as functions of temperature are calculated for majorite^pyrope garnets from new and previous infrared reflectivity and Raman scattering data. The thermodynamic properties, including the effect of cation disorder, vary by less than 4% over this binary, whereas k0 changes by s 400% due to cation disord...

W.L. Griffin, Suzanne Y. O'Reilly and N.J. Pearson GEMOC, Dept of Earth and Planetary Sciences, Macquarie University, NSW 2109, Australia [email protected] It has become conventional wisdom that xenoliths of eclogite and garnet pyroxenite derived from cratonic subcontinental lithospheric mantle (SCLM) represent fragments of subducted ocean floor, implying that the SCLM has grown by a litho...