New polysiloxane oligomers containing phosphorus, 6-(2-(dihydroxy(methyl)silyl)ethyl)dibenzo[c,e][1,2]oxaphosphinine 6-oxide (DOPO-VMDMS), have been synthetized and grafted to the remaining hydroxyl groups of alkyd resins in order obtain hybrid with flame retardant properties. These silicone demonstrated better drying time, gloss chemical resistance than reference without DOPO-VMDMS. Moreover, ...