نتایج جستجو برای: enzymatic deoxygenation
تعداد نتایج: 56232 فیلتر نتایج به سال:
in order to estimate the reducing sugar in tubers of potato by using a manual glucose determiner, an experiment was conducted in factorial arrangement based on completely randomized design with three replications. in this research reducing sugar of four cultivars of potato – agria, sante, with two methods: enzymatic and a manual glucose determiner. the results picaso and kizer – that maintained...
In sickle cell anemia, dehydrated erythrocytes (SS RBC) are involved in the propagation of the vasoocclusive process, which results in the most severe complication in sickle cell disease (e.g. stroke). Deoxygenation leads to red cell dehydration, and hence increases the rate of hemoglobin S (HbS) polymer formation, which subsequently sickles the cell and retards RBC transit through the microvas...
BACKGROUND Type 1 diabetic patients and non-diabetic patients were referred for evaluation for chronic exertional compartment syndrome (CECS) based on clinical examination and complaints of activity-related leg pain in the region of the tibialis anterior muscle. Previous studies using near-infrared spectroscopy (NIRS) showed greater deoxygenation during exercise for CECS patients versus healthy...
A new application for glycerol that expands its possibilities apart from green solvent and precursor of value-added products has been demonstrated. Simple, easily available, and environmentally friendly dioxomolybdenum(VI) complexes are highly efficient catalysts for the chemoselective sulfoxide deoxygenation with this biomass-derived chemical feedstock. Both refined glycerol and crude glycerin 10
Ketones are efficiently deoxygenated in the presence of silane using highly electrophilic phosphonium cation (EPC) salts as catalysts, thus affording the corresponding alkane and siloxane. The influence of distinct substitution patterns on the catalytic effectiveness of several EPCs was evaluated. The deoxygenation mechanism was probed by DFT methods.
Abstract The ongoing oceanic oxygen loss will have a profound impact on the distribution and density of life Earth. However, drivers initiation termination global deoxygenation are poorly understood. Here we present thallium isotope record that reveals three rapid (50 k.y.) intervals during mid-Cretaceous postdate massive volcanism by at least 1 m.y. New strontium data reveal gradually enhanced...
Considerable interindividual differences in the Q˙-V˙O2 relationship during exercise have been documented but implications for submaximal exercise tolerance have not been considered. We tested the hypothesis that these interindividual differences were associated with differences in exercising muscle deoxygenation and ratings of perceived exertion (RPE) across a range of submaximal exercise inte...
In this study, we used a recently developed nuclear magnetic resonance (NMR) technique to measure ionized calcium in sickle erythrocytes. The NMR technique, which involves 19F NMR studies of a fluorinated calcium chelator quinMF, [2-(2-amino-4-methyl-5-fluorophenoxy)methyl-8-aminoquinoline-N,N,N',N'- tetraacetic acid] provides a novel approach to the study of ionized calcium in erythrocytes sin...
Near-infrared spectroscopy (NIRS) could allow insights into controversial issues related to blood lactate concentration ([La](b)) increases at submaximal workloads (). We combined, on five well-trained subjects [mountain climbers; peak O(2) consumption (VO(2peak)), 51.0 +/- 4.2 (SD) ml. kg(-1). min(-1)] performing incremental exercise on a cycle ergometer (30 W added every 4 min up to voluntary...
Carbon-oxygen single bonds are ubiquitous in natural products whereas efficient methods for their reductive defunctionalization are rare. In this work an environmentally benign protocol for the activation of carbon-oxygen single bonds of alcohols towards a reductive bond cleavage under visible light photocatalysis was developed. Alcohols were activated as 3,5-bis(trifluoromethyl)-substituted be...
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