A recently introduced empirical nucleophilicity index for a series of nand p-nucleophiles was evaluated. The index is based on the frontier molecular orbital information of the nucleophile and its electrophilic partner. The model is validated against kinetic data of alkenes, phosphanes, phosphites and amines interacting with the corresponding electrophilic partner. The predictive character of t...

In this research, the effect of wood species and particle size on mechanicalproperties of wood plastic composites (WPC) made of fir (Abies alba) and beech(Fagus orientalis L.) sawdust and high density polyethylene (HDPE) wereinvestigated. Wood plastic composite (WPC) were made with 30% HDPE in abatch process at 185˚C, at two particle sizes of 40 mesh and 80 mesh. Maleicanhydride polypropylene (...

Interfacial strength between polymeric matrix and natural filler reinforcement has direct effects on the properties of wood plastic composites. There are some approaches to improve the interfacial adhesion between two phases in wood plastic composites. One of them is using coupling agents to improve the composite properties. In this study, the effect of maleic anhydride as a coupling agent on t...

We report the first enantioselective organocatalyzed domino synthesis of azepane moieties. This temporary-bridge strategy is based on a conceptually original annulation of ambident electrophilic and 1,4-bis-nucleophilic α-ketoamides with 1,3-bis-electrophilic enals. The obtained oxygen-bridged azepanes can be selectively transformed into optically active azepanone, azepanol or azepanedione deri...

Novel butterfly-shaped, highly fluorescent stable monomers of the type 7-tert-butyl-1,3,5,9-tetrakisarylpyrene were synthesized by the Suzuki-Miyaura coupling reaction of the new bromopyrene derivative 7-tert-butyl-1,3, 5,9-tetrabromopyrene with the corresponding arylboronic acids. The design and synthesis of efficient electroluminescent materials based on polyaromatic hydrocarbons (PAH) has be...

Circumtrindene (6, C36H12), one of the largest open geodesic polyarenes ever reported, exhibits fullerene-like reactivity at its interior carbon atoms, whereas its edge carbons react like those of planar polycyclic aromatic hydrocarbons (PAHs). The Bingel-Hirsch and Prato reactions - two traditional methods for fullerene functionalization - afford derivatives of circumtrindene with one of the i...

Magnesium metal is an ideal rechargeable battery anode material because of its high volumetric energy density, high negative reduction potential and natural abundance. Coupling Mg with high capacity, low-cost cathode materials such as electrophilic sulphur is only possible with a non-nucleophilic electrolyte. Here we show how the crystallization of the electrochemically active species formed fr...